How do I manage this waste stream?
Practical advice on how to manage, recycle, or dispose of common wastes
at Brookhaven
Pollution Prevention Home |
EWMS Home
Note: Advice on waste disposal and management is for typical waste streams. Wastes
contaminated with hazardous or radioactive materials may require additional controls.
Unused acids that have not expired can be made available
to the laboratory community for use via the
Chemical
Management Systems "Chemical Exchange" program.
I. Disposal via the sink
Any material disposed to the sink constitutes a liquid effluent. Requirements for
releasing liquid effluents are contained in the BNL Standards Based Management System
subject area entitled,
Liquid Effluents.
Some liquid effluents may contain material not listed on the
sink releasable chemical list,
but may be sink releasable. These effluents must be evaluated by the subject matter expert
in the Environmental and Waste Management Services Division to determine whether the effluent is acceptable for
sink release. The procedure for having a liquid effluent evaluated for sink release are
contained in the above reference subject area, or contact your
Environmental Compliance
Representative for help.
Small quantities of certain acids can be neutralized by knowledgeable staff and
disposed to the sink following the guidance in Neutralization. Contact the
Environmental Compliance
Representative for assistance in determining whether this is advisable.
II. Disposal via the Environmental and Waste Management
Services Division
Acids which can not be disposed in the sink shall be accumulated, stored, labeled and
disposed of per the requirements described in the BNL Standards Based Management System
subject area entitled
Hazardous Waste
III. Acid waste storage issues:
The following acids should not be stored together, because they are incompatible:
- Acetic Acid, Chromic Acid and Nitric Acid
- Acetic Acid and Perchloric Acid
- Nitric Acid and Hydrocyanic Acid
Refer to the exhibit in the Hazardous Waste subject area "Examples of Incompatible
Chemicals" for a more complete list of chemical incompatibilities, or contact
your Environmental Compliance
Representative or Waste Management Representative.

Aerosol Cans
There are
two options for managing aerosol cans: Either as a recycled material or as a
hazardous waste.
Management as a Recycled Material
Empty and
release all pressure from the can by puncturing using an approved can-puncturer.
Aerosol cans containing highly toxic chemicals (a.k.a. acute or RCRA P-wastes,
or pesticides/herbicides/rodenticides) may NOT be punctured and must be
managed as hazardous wastes. Additionally, generators may NOT puncture
cans using other than an approved device as it may be UNSAFE.
NOTE:
Un-punctured, depressurized cans (i.e. will no longer discharge contents) should
not be assumed to be, nor managed as, empty or scrap as they may still contain
product.
Once the
aerosol can is punctured and allowed to thoroughly drain of residual liquids,
the metal cans may be recycled as scrap metal as per the
Industrial Waste SBMS Subject Area.
Call your ESH Coordinator, ECR or WMR to determine if a can-puncturer is
available to your group.
Management as Hazardous Waste
Instead of
using an approved can-puncturer, generators have the option of managing the cans
as hazardous waste (i.e. ignitable, toxic; depending on the type of contents
and/or propellant). Cans must be managed as per the
Hazardous Waste SBMS Subject Area and
generators may accumulate them in a satellite area or inside a 90-Day Hazardous
Waste Accumulation Area.
Note:
aerosol cans containing materials that transform into solids or semi-solids upon
discharge (such as foam insulation, sealants, etc) cannot be punctured as it
clogs the approved can puncturer. Also, cans not containing hazardous
propellants and/or hazardous components (e.g. shaving cream cans) do not require
puncturing and can be handled as scrap metal.

A recyclable material; should be disposed of in dedicated
recycling containers, located in the Cafeteria (Berkner Hall) or in Building lunchrooms or
kitchenettes. You may request an aluminum can recycling container from the
Recycling Coordinator.

Waste that does not contain another hazardous material
and contains asbestos becomes classified as asbestos containing material waste (ACM).
Special programs on the federal, state, and Laboratory level regulate and/or manage
asbestos waste depending on the form and concentration of asbestos in waste. Individuals
who are involved with asbestos and ACM abatement, removal, and disposal shall obtain
specific regulatory-based training and certification. BNL requires all ACM removal and
waste activity to be coordinated by the Plant Engineering Division (PE). Contact
PEs
Asbestos
Abatement Coordinator on extension
x5284 to arrange for the removal and disposal
of ACM.

Antifreeze (typically ethylene glycol or propylene glycol) is usually
characterized as "Industrial Waste". Collect spent antifreeze in an appropriate
container for transfer to Environmental and Waste Management Services Division. Complete the
Nonradioactive Waste Control Form,
label the container with a 'Non-Hazardous Waste' label and move the container to the
90-Day Accumulation Area.

Batteries
may or may not be "universal wastes"
depending on the type.
- Alkaline
batteries - Currently manufactured alkaline batteries (post-1995) may be disposed
of in the regular garbage (no hazardous constituents). Old stockpiled batteries (pre-1995)
should be disposed of as universal waste
(see note below describing new Universal Waste regulations).
- Button
Cells (silver oxide and/or mercury oxide = calculator, watches, etc.)
- These
batteries are typically characterized as "Universal Waste" due to the silver or
mercury content. These batteries should be segregated by content in the satellite
accumulation area. Complete the
Nonradioactive Waste Control Form, label the container as per the above
and move the container to the 90-Day Accumulation Area.
- Lead
Acid batteries (automotive type) automotive batteries should be brought to
the BNL Motor Pool (Building 423) for proper recycling. Note: Do not empty the liquid
contents of the battery.
- Lead
Containing batteries (D-cell type) typically characterized as
"Universal Waste" due to the lead content. Collect batteries as per the
universal waste requirements below and transfer
to Environmental and Waste Management Services Division. Complete the
Nonradioactive Waste Control Form, and move the container to the 90-Day Accumulation
Area.
- Lithium
batteries typically characterized as "Universal Waste" due to
the lithium content. Collect batteries in an appropriate container for transfer to
Environmental and Waste Management Services Division.
Complete the
Nonradioactive Waste Control Form, label the container as per the above and move the
container to the 90-Day Accumulation Area.
- NiCad
(nickel/cadmium = power tool batteries/power packs) typically
characterized as "Universal Waste"
due to the cadmium content. Collect batteries in an appropriate container as per the above
for transfer to Environmental and Waste Management Services Division. Complete the
Nonradioactive Waste Control Form, and move the container to the 90-Day
Accumulation Area.
NOTE:
New York State Department of Conservation regulations regarding batteries containing
hazardous constituents (e.g. lead, lithium, mercury/mercury oxide, nickel-cadmium,
silver/silver oxide, etc.) have recently changed to facilitate recycling. These batteries
are considered universal wastes, NOT hazardous wastes. Storage
containers for waste batteries must be:
- Labeled
with Universal Waste-battery(ies) or Waste Battery(ies) or
Used Battery(ies),
- Marked
with the type of battery (e.g. mercury, lithium, mercury, etc.),
- Dated
when the first battery was added to the container,
- Compatible
with the battery(ies) stored (e.g. plastic container for lead-acid batteries),
- Structurally
sound without major defects, and
- Closed
at all times unless adding a battery(ies)
Generators
may keep the above batteries for up to one (1) year from the time the first battery was
placed into the container until shipped off-site for disposal/recycling. Generators must
also allot enough time for Environmental and Waste Management Services Division to process the batteries and ship them off site so as not
to exceed the 1 year limit.
Leaking
batteries must NOT be handled as universal wastes. Since batteries may contain
hazardous materials, contact the ECR for guidance. Batteries that are Universal Waste must
be segregated by type in the satellite accumulation area.

Bottles (Beverage)
A recyclable material; should be disposed of in dedicated
recycling containers, located in the Cafeteria (Berkner Hall) or in Building lunchrooms or
kitchenettes. You may request a yellow bottle/can recycling container from the
Recycling Coordinator.

To protect janitorial and waste handling staff from injury, please place glass,
whether broken or intact, into a rigid outer container (such as plasticware or cardboard)
marked with the works "glass" or "broken glass". Glass packaged in
this manner can then be placed into regular trash receptacles. Office, lounge and food
areas should have recycling bins for unbroken glass containers such as soda bottles. If
the waste glassware was used to store a chemical, see Empty Chemical Containers for
guidance on proper disposal.

Caustic Wastes
I. Disposal via the sink
Unused bases that have not expired can be made available to the laboratory community
for use via the Chemical Management
Systems "Chemical Exchange" program.
Any material disposed to the sink constitutes a liquid effluent. Requirements for
releasing liquid effluents are contained in the BNL Standards Based Management System
subject area entitled,
Liquid
Effluents.
Some liquid effluents may contain material not listed on the
sink releasable chemical list,
but may be sink releasable. These effluents must be evaluated by the subject matter expert
in the Environmental and Waste Management Services Division to determine whether the effluent is acceptable for
sink release. The procedure for having a liquid effluent evaluated for sink release are
contained in the above reference subject area, or contact your
Environmental Compliance
Representative for help.
Small quantities of certain bases can be neutralized by knowledgeable staff and
disposed to the sink following the guidance in
Neutralization of Corrosive Wastes.
II. Disposal via the Environmental and
Waste Management Services Division
Caustic wastes that cannot be disposed of to the sink shall be accumulated, stored,
labeled and disposed of per requirements described in the BNL Standards Based Management
System subject area entitled
Hazardous Waste
Management
Refer to the exhibit in the Hazardous Waste subject area "Examples of Incompatible
Chemicals" for a more complete list of chemical incompatibilities, or contact
your Environmental Compliance
Representative or Waste Management Representative.

Unused chemicals that have not expired can be made available to
the laboratory community for use via the
"Chemical
Management Systems "Chemical Exchange" program.
Please search the list of waste management techniques for the specific type of waste
stream that you have.
General disposal instructions for chemicals:
- Waste chemicals must be accumulated, stored, labeled and disposed of per the
requirements described in the BNL Standards Based Management System subject area entitled
Hazardous Waste.
- Refer to the exhibit in the Hazardous Waste Management subject area titled
"Examples of Incompatible
Chemicals" for a list of chemicals that should not be stored together.
- Refer to the exhibit in the Hazardous Waste subject area titled "Sink Releasable Chemical List",
for guidance regarding chemicals that can be discharged to the sink.
Questions? Contact your
Environmental
Compliance Representative or Waste Management Representative.

See Solvents

- Compactable Radioactive Waste refers to items that are easily
crushed in a compactor. Examples include paper; rags; clothing; respirators; empty
glassware; easily crushable, empty, lightweight metal labware; and empty crushable plastic
labware.
- Compactable Radioactive Waste shall be shall be accumulated, stored, labeled and
disposed of per requirements described in the BNL Standards Based Management System
subject area entitled
Radioactive
Waste Management.

Computers and related equipment are considered sensitive
items, which are controlled and inventoried by Property Management, and hence
need to follow a specific protocol for transfer/disposal. The first thing to do
is contact your Department’s Property Representative (see
https://sbms.bnl.gov/SupportServices.cfm?SS=P). The Property Representative
will aid you in determining the proper SOP’s to follow. The hierarchy of
computer / electronic equipment disposal is:
- Internal division transfer – transferred to another
individual with the Department
- Intra-Lab transfer – transferred to another Department
- Transfer to excess – usable equipment which may be
transferred to a non for profit school participating in the Computers for
Learning Program
-
Sent to a
recycler for disposal

Controlled substances designated as waste are rarely managed by
BNL and are handled on a case-by-case basis. When you designate controlled substances as
waste, send a complete inventory (Chemical Name, CAS No., and Weight (solid) or Volume
(liquid) of Waste) to a Environmental and Waste Management Services Division Generator Services Supervisor.
Environmental and Waste Management Services Division will contact the Drug
Enforcement Agency (DEA) on your behalf. You will be required to complete a DEA Form 41
and may be interviewed by a local DEA Agent. Although Environmental and Waste
Management Services Division will arrange transportation and
disposal of the materials on your behalf, Environmental and Waste Management
Services Division does not fund disposal of controlled
substances. You will be required to pay for transportation and disposal costs. You may
also be required to witness the destruction of the controlled substances at the disposal
facility.

See Acids and/or Caustic
Wastes

If you have corrosive waste that is rad contaminated, see Neutralization of
Radioactive Corrosive Waste.
Small quantities of acids or caustic waste can be neutralized by knowledgeable staff to
a pH of 6-8 in the laboratory and disposed to the sink, if safe practices are followed
during the neutralization. The following guidelines apply:
- The concentration of the solution being neutralized should be <1 Normal.
- The volume of the solution should be < 1 Liter.
- The acid/caustic cannot contain contaminates, especially halogenated organics, oils or
metals such as arsenic, barium, cadmium, chromium, lead, mercury, selenium, or silver.
- All constituents of the neutralized solution must be listed on the
Sink Releasable Chemical List. As
per this list, some uncontaminated acids can be discharged into the sink directly, with
running water.
- Acids that cannot be neutralized and sink disposed are chromic acid, hydrofluoric and
fluoboric acid.
Any liquid disposed to the sink constitutes a liquid effluent. Requirements for
releasing liquid effluents are contained in the BNL Standards Based Management System
subject area entitled
Liquid
Effluents.
There are special cases when an effluent that contains material not listed on the sink
releasable chemical list is sink releasable. These wastes must be evaluated by the subject
matter expert in the Environmental and Waste Management Services Division to determine whether it is acceptable
for sink release. The procedure for having a liquid effluent evaluated for sink release is
contained in the above referenced Liquid Effluent subject area. If you have questions
regarding liquid effluent, or require help identifying potential sink releasable
effluents, contact your Environmental
Compliance Representative or your Waste Management Representative.

Corrugated Cardboard
Corrugated Cardboard is a recyclable material; if large
quantities, locate the dumpster labeled as "Cardboard Only" and dispose of
therein if small quantities, leave the contents outside of your office door and
custodial services will recycle it.

Unwanted, Non-Radioactive cylinders, including lecture bottles, may be managed
in one of the following ways. For cylinders that are in good condition and are properly
marked to identify the contents, contact the Cylinder Warehouse (ext. 2964) managed by the
Procurement & Property Management Division to try and arrange for return of the
cylinder(s) to the supplier/manufacturer. See
the Supply & Material group procedure
for tagging and control of gas cylinders.
If the cylinder cannot be returned to the supplier/manufacturer, then
cylinders must be disposed through the Environmental and
Waste Management Services Division. See the
Hazardous Waste Management
subject area for guidance. If the cylinder is in poor condition and/or its
contents are uncertain, contact the Environmental and Waste
Management Services Division for characterization/disposal guidance.
The two most common broad categories of part-washing methods are;
- Aqueous-based cleaning
- Solvent-based cleaning
Use part washing solutions in this order of preference:
- Aqueous cleaning solutions, like alconox, trisodium phosphate (Spic & Span), Simple
Green, etc.
- High flash point mineral spirits cleaners, like kerosene
- Non-Chlorinated solvent cleaners, like ethanol or isopropanol. DON'T use toluene, methyl
ethyl ketone (MEK), benzene, 2-ethoxyethanol, or 2-nitropropane if at all possible. These
compounds are listed hazardous wastes.
- Chlorinated solvent cleaners should be the last resort. These are typically all
hazardous wastes.
Disposal of part washing wastes varies depending on the type of cleaner used and what
has been cleaned off the parts. Certain parts washers are Hazardous Wastes when disposed
while others are Industrial Wastes. Additionally, rags and wipes contaminated with certain
degreasers are also considered Hazardous Waste. See the guidance below to determine the
best method for disposal of the materials used.
Aqueous-based Part Washing Wastes
Typically involves;
- Detergents and water
- Aqueous solutions of acids or bases
Typically disposal recommendations are;
- Detergent-based aqueous cleaning solutions are typically not hazardous wastes. Often
they are releasable to the sanitary system with the approval of the
Environmental and Waste Management Services Division (see the
Liquid
Effluents subject area). If they were used to clean gross amounts of oil and grease, they may
require disposal as industrial wastes, unless it is contaminated with hazardous or
radioactive materials in which case it should be managed accordingly. A secondary option
to disposal as an Industrial waste is to contact your
ECR to see if the waste can be
disposed of through the Central Shops evaporator.
- Aqueous solutions of acidic or basic cleansers are hazardous wastes IF the pH is less
than or equal to 2.0 or greater than or equal to 12.5. You may neutralize the pH to 6-8
range, in which case the solution could be handled as an industrial waste, unless it is
contaminated with hazardous or radioactive materials in which case it should be managed
accordingly.
Solvent-based Part Washing
- High flash point mineral spirit based cleaners (e.g., kerosene) should be collected for
disposal as industrial waste, unless it is contaminated with hazardous or radioactive
materials in which case it should be managed accordingly.
- Non-Chlorinated solvent cleaners (e.g., ethanol, isopropanol) should be collected as
hazardous waste due to ignitability. Rags and wipes contaminated with these solvents may
be disposed in the trash PROVIDED THEY ARE DRY. Saturated rags/wipes should be collected
and disposed as hazardous wastes.
- Halogenated Solvents (e.g., freon,
1,1,1-Trichloroethane, perchloroethylene, etc.) must be disposed of as Hazardous Wastes.
In addition, any rags or other items contaminated with the halogenated solvents must be
disposed of as Hazardous Waste

Empty
drums from virgin products (which have a deposit fee) may be sent back to the manufacturer
if:
- the drum is kept in a secure location;
- the user can certify that the drum is
not contaminated with other product (i.e, no other materials were placed in the drum for
short-term storage);
- the drum was not stored in a
suspect area; and
- the drum is not activated or contaminated with radioactivity
In order to
be able to ship the drums back, the user will need approval and authorization from both
PPM and EWMSD. You may contact your ECR for
more information.
Drums, which
are not activated or contaminated with radioactivity, were not stored in a suspect
area and did not contain hazardous constituents, may be sent to the clean metals
scrap yard for recycling. The user will need
to provide PPM with a Process Knowledge Certification Form.
Drums, which
are not activated or contaminated with radioactivity and did not contain hazardous
constituents but were stored in a suspect area, may be sent to the suspect
metals scrap yard. The user will need to
provide PPM with a Process Knowledge Certification Form.
Drums, which
are activated or contaminated with radioactivity and/or contained hazardous materials,
will need to be sent to the Environmental and Waste Management
Services Division for disposal.
The user will need to provide Environmental and Waste Management
Services Division with a
Nonradioactive
Waste Control Form and Process
Knowledge Certification Form.

Empty Chemical Containers and Drums
See Chemical Bottle Collection Program for empty chemical
containers.
See Drums

See also Computers and Related Equipment
Electrical equipment (e.g., motors, control panels, relays, switches, cables, meters,
gauges, etc.) that is damaged, unusable, or has no intrinsic value may be disposed,
salvaged, or recycled only when all hazardous material (e.g., asbestos, lead, oils, lead,
PCBs, freon, mercury) has been removed from equipment and has been surveyed and certified
as radiologically clean by the Radiological Controls Division.
Electrical equipment disposal may be subject to BNL sensitive and capital property
management controls. The BNL Administrative Services Divisions Supply and Materiel
Property Management Section is responsible for excessing or salvaging all non-hazardous
material and equipment released by BNL organizations for disposal. Contact extension 2977
for information and instruction regarding property management controls for electrical
equipment that may be bar-coded sensitive or capital equipment.
To dispose of non-hazardous electrical equipment, an Equipment Movement Request Form
available from your department or division administrative office shall be completed and
returned to the Property Management section located in Building 211.
See Organic Peroxides and
Peroxide Forming Compounds

Ethidium
bromide (EtBr; 2,7-diamino-10-ethyl-phenylphenanthridinium bromide, CAS #1239-45-8) is
used routinely by molecular biologists in visualization of nucleic acids in gels. Wastes contaminated with ethidium bromide are not
regulated as a hazardous waste, however the mutagenic properties of this substance may
present a hazard if it is poured down the drain untreated or is disposed in the trash. It
is therefore BNL practice to collect EtBr wastes as Industrial wastes.
Electrophoresis
gels contaminated with EtBr should be collected in a container with a lid and a green
Non-hazardous waste label. The material
should be disposed as an Industrial Waste following the
Industrial Waste subject
area.
Solutions
containing EtBr
*should either be
treated or collected for disposal as an industrial waste.
Treatment of EtBr is encouraged to reduce the amount of waste being
disposed. Appropriate gloves should be worn when
working with EtBr.
*solutions refers to aqueous based
non-hazardous solutions.
Treatment
of Aqueous Solutions of EtBr:
There are
several methods for treatment of aqueous solutions with EtBr waste. BNL encourages the use of activated charcoal for
decontamination and does not permit treatment methods that utilize bleach.
Method 1:
Activated Charcoal**
- Add 100 mg activated charcoal
powder per 100 ml of solution to be decontaminated (dilute solutions ~0.5 ug/ml).
- Store solution for a minimum of
1 hour at room temperature, with occasional shaking or overnight stirring.
- Filter through Whatman No. 1
filter paper and discard the filtrate to the sanitary sewer system.
- Seal the filter and charcoal in
a plastic bag for disposal as an industrial waste following the
Hazardous Waste
Management subject area. Multiple filters with charcoal may be stored in
each bag.
**This information was taken from http://res2.agr.ca/winnipeg/decontam.htm
(Winnipeg Cereal Research Center) and http://www.man.ac.uk/policies/68.htm
(University of Manchester)
Method
2: Activated Carbon Kit
- Purchase a gel destaining
bag kit*
- Drop the bag into the solution
(usually overnight). Review manufacturer directions.
Typically each bag adsorbs 10 mg EtBr.
- Occasionally shake or rotate
solution. Overnight stirring is acceptable.
- Discard wastewater to sanitary
sewer.
- Collect bag for disposal as an
industrial waste following the
Hazardous
Waste Management subject
area.
*Some sources of destaining
bag kits include:
- Scienceware Gel Destaining Bags (www.bel-art.com, 1-800-423-5278, F13555-0000)
- EtBr Green Bag Kit by Qbiogene
(www.bio101.com)
- Thomas Scientific Gel
Destaining Bags (4313L01)
Contact Supply and Material
to dispose of excess equipment.

Gasoline is characterized as Hazardous Waste due to ignitability. Collect waste
gasoline in an appropriate container for transfer to Environmental and Waste
Management Services Division. Complete the
Nonradioactive
Waste Control Form, label the container with a 'Hazardous Waste' label and move
the container to the 90-Day Accumulation Area.

Type dependent:
- Beverage containers - should be disposed of in dedicated recycling containers, located
in the Cafeteria (Berkner Hall) or in Building lunchrooms or kitchenettes.
- Lab glassware (uncontaminated - beakers, Petrie dishes, etc.) dispose of in
dedicated lab glass bags available from the custodial staff.
- Manufacturers chemical bottles should be reused to store, collect and
disposed of waste chemical material. If there is an overabundance of manufactures
chemical bottles, they should be disposed of in dedicated lab glass bags.
- Do not dispose of glass into the regular trash.

Hazardous waste must be managed through, or in conjunction with, BNLs
Environmental and Waste
Management Services Division. See the SBMS
Hazardous
Waste Management subject area for detailed guidance on the proper storage,
identification, and documentation required prior to pick-up by Environmental and
Waste Management Services Division.
In general, wastes are regulated hazardous wastes if they are listed in the
regulations (40 CFR Part 261 Subpart D, Lists of Hazardous Waste) or exhibit one or more
characteristics of hazardous waste (40 CFR Part 261 Subpart C, Characteristics of
Hazardous Waste). Your Environmental
Compliance Representative or Waste
Management Representative has expertise in determining whether wastes are hazardous.

The
Industrial Waste
subject area details the requirements when managing Industrial Waste.
Questions regarding Industrial Waste can also be forwarded to the Environmental
and Waste Management Services Division. Your
Environmental Compliance
Representative or your Waste Management Representative can help you identify common
industrial wastes such as uncontaminated photographic developer and uncontaminated pump
oil. Your ECR or WMR can also help identify potential industrial wastes that are good
candidates for evaluation by the Environmental and Waste Management
Services Division and help with the evaluation process.
Guidance pertaining to liquid Industrial Waste:
Liquid industrial waste may only be discharged to the sanitary system if it meets the
requirements for discharge dictated by BNLs SPDES Permit. See the
Liquid Effluents subject area for
more information. All Requests for discharge to the
sanitary system must be made on a
Liquid Effluent Evaluation Form found in the
Liquid Effluents
subject area.

Uncontaminated clean lead can be recycled
through the Procurement and Property Management (PPM) Division. The lead should be stored indoors to protect it
from the elements. Call PPM at ext. 7238 to
make arrangements for pick up of the material. Prior
to pick up a completed Process Knowledge Certification form will be needed.
Contaminated
lead (activated or radioactive) should be directed to the
Environmental and Waste Management Services Division.

LBP and debris, depending on sample analysis data, most
likely are considered a hazardous waste when no longer useable and/or have been scraped or
removed from another substrate.
LBP and debris that exceeds the hazardous constituent threshold shall be identified,
packaged, labeled, stored, and managed in accordance with the requirements contained in
the BNL Standards Based Management System (SBMS) subject area entitled,
Hazardous Waste
Management
For additional information regarding LBP scraping, removal, and disposal contact the
Plant Engineering Division (EP) Operations and Maintenance Sections Building
Maintenance and Services Group on extension 3981 or review/download EPs internal
web-based environmental safety and health procedure. Reference BNL hyperlink: http://epweb.pe.bnl.gov/Ep_Procedures/procedure/ep-es&h/ESH201g.DOC
and http://epweb.pe.bnl.gov/Ep_Procedures/procedure/ep-es&h/ESH201h.DOC

Laser Dye Solvent Wastes
See Solvents

Fluorescent &
Mercury-Containing (high mercury & green-tipped) lamps (Non-radioactive)
Fluorescent bulbs (high mercury/non-green-tip bulbs) must be managed as a
“Universal Wastes” (see note below). Low Mercury type (green-tips) bulbs must
NOT be disposed of in the trash. These bulbs can be handled as “Universal
Wastes” or, alternatively, as non-hazardous “Industrial Wastes” Refer
to the Hazardous Waste
Management subject area or the
Industrial Waste
subject area for more details.
For info on mercury-containing consumer products, see “Mercury” section in this
document.
Non-Fluorescent
and non-mercury light bulbs, lamps and other light emitting devices
(Non-radioactive)
Evaluate the
lights for hazardous constituents (lead, etc.). If no hazardous constituents are
present, handle the bulbs/lamps/lights as solid waste. If hazardous constituents
are present, handle them as hazardous wastes.
Refer
to the Hazardous Waste
Management subject area for more details.
Radioactive light
bulbs, lamps and other light emitting devices
Evaluate the
lights for hazardous constituents (lead, mercury, etc.). If no hazardous
constituents are present, segregate from all other waste types and handle the
lights as radioactive waste [refer to the
Radioactive Waste
Management subject area
for more detail]. If hazardous constituents are present, handle the lights as
mixed waste [refer to the
Mixed Waste
Management subject area for more detail].
NOTE:
The New York State Department of Conservation regulations allow lamps containing
hazardous constituents (e.g. lead, mercury, etc.) to be managed according to
Universal Waste regulations. Management of the above
wastes as Universal Waste allows for alternative management as compared to
hazardous waste requirements so as to facilitate off-site recycling. Storage
containers for universal waste mercury lamps/bulbs must be:
-
Labeled with “Universal Waste-Lamps">
-
Marked with the type
of Lamp (e.g. mercury, lead, etc.),
-
Dated when the first lamp was added to the
container,
-
Closed at all times unless adding a Lamp
Generators must either submit a
Nonradioactive
Waste Control Form for the above bulbs within 6 months of the
above accumulation start date to the Environmental and Waste
Management Services Division. (EWMSD), or contact the Plant Engineering
Waste Management Representative for transfer to the on-site, designated
accumulation area.
Any broken mercury bulbs MUST NOT be handled as
“Universal Wastes”. Broken bulbs MUST be
handled as hazardous wastes.
Magazines
A recyclable material; dispose of in one of the blue plastic containers with the
Town of Brookhaven "Community Recycling" label.

The following mercury-containing items MUST be either handled
as "Universal Waste", "Hazardous Waste", non-hazardous "Industrial Waste", or be
recycled (if no other use), but in no case can they be thrown into the normal
municipal trash:
- Thermostats - handle as "Universal Waste";
- Batteries containing mercury - handle as "Universal Waste";
- Electronics equipment containing liquid mercury components - remove
components before disposing and handle these as "Hazardous Waste" (Note:
if being routed for reuse/donation, then removal is not necessary);
- Low-mercury/green-tipped fluorescent light bulbs - handle as “Universal
Wastes”, non-hazardous "Industrial Waste" or recycle;
- Thermometers - handle as "Hazardous Wastes";
- Miscellaneous mercury-containing novelty items - handle as “Hazardous
wastes” or recycle;
- Medical equipment (e.g. blood pressure sphygmomanometers) - remove liquid
mercury components and handle mercury as "Hazardous Wastes". Associated glass
and other components contaminated with mercury must be handled as "hazardous
waste"
NYS has recently passed the “NYS Mercury-Containing Consumer Products Law”
that prohibits the disposal of any mercury-containing item(s) into the normal
municipal trash.
Any recycling and/or removal of mercury-containing items from specialized
equipment requires adequate work planning and controls for personnel safety- see
pertinent SBMS subject areas.
For additional information on the handling of Universal, Hazardous, and
Industrial Wastes, see
Hazardous Waste
Management subject
area or the
Industrial Waste
subject area for more details.
Low-mercury, green-tipped fluorescent light bulbs are currently managed
through Plant Engineering. See EP’s Waste Management Representative (WMR) for
additional information.

Metal
Chips & Turnings From Machining Operations
Routine metal chips or turnings from steel, stainless steel, aluminum,
brass, and copper machining operations that do not contain hazardous material such as
lead, cadmium, chromium, beryllium or uranium should be collected in containers at the
point of generation. The metal should be disposed through the scrap metal program
administered by the Administrative Services Divisions Supply and Materiel (S&M)
Section. After accumulating machined chips and turnings, contact the S&M scrap metal coordinator on
extension 7238 to arrange for the direct pick-up by a BNL scrap metal contractor at the
point of generation and accumulation.
Note: All scrap metal originating from a BNL radiologically controlled area shall be
surveyed and certified radiologically clean by the BNL Radiological Controls Division. All
metal subsequently passes though the BNL truck portal monitor radiation detectors to
ensure no release of radioactivity off-site.

A recyclable material; dispose of in one of the blue plastic containers with the
Town of Brookhaven "Community Recycling" label.
Oils are typically characterized as "Industrial
Waste". They should be placed in an appropriate container for transfer to
Environmental and Waste Management Services Division.
Complete the
Nonradioactive Waste Control Form, label the container with a 'Non-Hazardous
Waste' label and move the container to the 90-Day Accumulation Area.
Note: Some oils may contain PCBs. Common sources of PCB contaminated oil include old
transformers and capacitors. Any oil that is not from a known source should be tested for
PCB contamination before disposal. PCB contaminated oil is Hazardous Waste. Refer to the PCB Waste section of the
Hazardous Waste Management subject area.

If you change your own oil in your vehicle, you have a responsibility to
properly manage the waste crankcase oil. Commercial service stations (including the
on-site station) that perform oil changes are required by NYS law to accept up to five
gallons of waste motor oil from the public at no cost. Additionally, many Town S.T.O.P.
programs have waste oil collection tanks. The oil should be poured into a container
labeled "Waste Oil" that can be sealed to prevent spillage during transport to
the service station. Notify the service station personnel that you would like them to
recycle your waste oil.
DO NOT just leave it without notifying them and
DO NOT pour waste oil on the
ground or into storm sewers.

Oil filters are typically characterized as "Industrial
Waste". They should be drained of free flowing oil (collect oil) and placed in an
appropriate container for transfer to Environmental and Waste Management
Services Division. Complete the
Nonradioactive
Waste Control Form,
label the container with a 'Non-Hazardous Waste' label and move the container to the
90-Day Accumulation Area.
The Staff Services Vehicle Maintenance Operation has an oil filter crusher that
squeezes the residual oil out of filters and reduces the volume by a factor of four. They
may accept drums of oil filters for crushing.

Oily rags that are NOT contaminated with hazardous waste (e.g., lead, mercury,
solvents), are "Industrial Waste" that cannot be
disposed in the regular trash. They must be collected in an appropriate container and
labeled with the 'Non-Hazardous Waste' lable (available from stock). Dispose of oily rags
through the Environmental and Waste Management
Services Division by completing a
Nonradioactive
Waste Control Form and
placing the container in the 90-Day Accumulation Area for pick-up.
If the oily rags are contaminated with Hazardous Waste (e.g., chlorinated solvents,
heavy metals, etc.) then the rags must be managed as Hazardous Waste. Collect the rags in
a container in a Satellite Accumulation Area. Label the container with a Hazardous Waste
Label and the words that describe the waste (e.g., "Chlorinated Solvent Contaminated
Rags"). Keep the container closed at all times except when adding or removing waste.
Dispose of through the Environmental and Waste Management
Services Division by completing a
Nonradioactive
Waste Control Form and
placing the container in the 90-Day Accumulation Area for pick-up. See the
Hazardous Waste Management
subject area for details.
If the oily rags are contaminated with PCBs, they are subject to management as a
Hazardous Waste. See the PCB
Waste Management section of the Hazardous Waste Management subject area.

Contact Supply and
Material to
dispose of excess equipment.

A recyclable material; dispose of in one of the blue plastic containers with the Town
of Brookhaven "Community Recycling" label.

Dispose of in the regular trash.

Peroxidizable compounds, absorb and react with oxygen to form potentially explosive
compounds with time. Exposure to air, heat and light accelerates these formations.
Containers of organic peroxides should be checked for age, signs of evaporation,
discoloration and crystal formation. If any of these conditions exist, please contact your
FS Representative immediately. Procedures for handling Peroxidizable compounds are
outlined below.
List of peroxidizable compounds Standard 2.1.1, page 6.
Precautionary Measures to be followed when handling and stabilizing peroxide forming
compounds:
- Although the volume of chemicals in these labs is relatively small, even minor
detonations can be very dangerous and can cause burns and serious injury from flying glass
and debris.
- If you are not familiar with handling these materials, contact the
the Environmental and Waste Management
Services
Division, your FS Representative or your
Environmental Compliance
Representative.
- If you are familiar with handling these materials, stabilize the material and move it to
an isolated location. Follow applicable IH procedures for handling these compounds,
available in the Environmental Health and Safety Standard 2.1.1, pages 5 9. Contact
the Environmental and Waste Management
Services Division, or your FS Representative for advice on how to stabilize the
material.
Once the material is stabilized, it should be managed as a hazardous waste, per the
requirements in the
Hazardous
Waste Management subject
area.

Orphan wastes include materials with no known or anticipated use whose
creator/generator cannot be identified or located to properly characterize the waste. To
facilitate the proper disposal of such materials characterization data (physical,
chemical, radiological) must be provided either through process knowledge, if available,
or analysis. For such materials, contact should be made with the
Environmental and Waste Management
Services Division and/or
Environmental Compliance
Representative to try and determine the necessary analysis for proper characterization
and the subsequent path for disposal. Note:
lack of a responsible individual does not relieve BNL of the requirements for proper
management. The Department or Division in possession of the waste is responsible for
properly managing the material pending transfer to the
Environmental and Waste Management Services Division.

Containers of used or leftover water-based paint (WBP)
can be left open to air dry then disposed through the municipal waste system (trash).
Based on the quantity accumulated, it may be possible for BNL to donate unused WBP to
external organizations. For information on donating unused WBP, contact the
Environmental and Waste Management Services Division, your
Environmental
Compliance Representative or the Plant Engineering Division Operations and Maintenance
Sections Building Maintenance and Services Group on extension 3981.
Containers of used or leftover oil or lead-based paint (LBP) are considered a hazardous
waste when no longer useable and shall be identified, packaged, labeled, stored, and
managed in accordance with the requirements contained in the BNL Standards Based
Management System (SBMS) subject area entitled,
Hazardous Waste Management

Paint Thinner
Containers of used or leftover paint thinner are
considered a hazardous waste due to ignitability when no longer useable and shall be
identified, packaged, labeled, stored, and managed in accordance with the requirements
contained in the BNL Standards Based Management System (SBMS) subject area entitled
Hazardous Waste
Management Label
the container with a Hazardous Waste label, keep the container closed. Complete a
Nonradioactive
Waste Control Form and move the container to the 90-Day Accumulation Area.

A recyclable material; dispose of in one of the blue plastic containers with the Town
of Brookhaven "Community Recycling" label.

Includes
items such as transformers, large capacitors (> 3 lbs. or >100in3.),
voltage/induction regulators, klystrons, hydraulic equipment, etc.
Non-radioactive
PCB equipment - If
the equipment is currently listed
on your facility’s PCB inventory, notify EWMSD with your intent to remove the
transformer from service. Then, determine the PCB concentration of the
dielectric fluid. If the PCB
concentration of the dielectric fluid is > 50 ppm PCB,
contact the Environmental and Waste Management
Services Division and/or the PCB SME for additional
guidance on treatment/disposal requirements (draining, solvent flushing for >
500 ppm, etc.) (reference 40 CFR 761.60). [refer to the Hazardous Waste subject
area section
on PCBs for more detail.]
Radioactive
PCB equipment - If the equipment is
currently listed on your facility’s PCB inventory, notify EWMSD with your intent
to remove the item from service. Then, determine the PCB concentration of the
dielectric fluid. If the PCB concentration of the dielectric fluid is >
50 ppm PCB, then contact the Environmental and Waste Management
Services Division and/or the PCB SME for
additional guidance on draining l fluids, treating the transformer. Note: the
fluids and equipment carcass are to be treated as mixed wastes [refer to the
Mixed Waste
Management subject area section on PCBs for more detail.]

Defined as oil and debris containing PCBs and includes waste
generated from the testing of PCB materials and empty containers once holding
PCB materials.
Non-radioactive
PCB oil (and other liquids) and debris - Determine
the PCB concentration of the source of PCB contamination. If unable to determine
the PCB concentration in the PCB source, test the materials for actual PCB
concentration. Treat the materials as hazardous waste [refer to the
Hazardous
Waste Management subject
area section on PCBs
for more detail.]
Radioactive
PCB oil (and other liquids) and debris - Determine
the PCB concentration of the source of PCB contamination. If unable to determine
the PCB concentration in the PCB source, test the materials for actual PCB
concentration. Treat the materials as Mixed Waste [refer to the
Mixed Waste
Management subject area section on PCBs for more detail.]

- Defined
as a capacitor < 3lbs. (1.36 kg) in total weight or < 100 in3
(1,639 cm3)
- NOTE:
Treat all leaking small capacitors and leaking light ballasts as
Large
Capacitors.
- Non-radioactive
small capacitors
- Refer
to the Hazardous
Waste Management subject
area section on PCBs for more detail.]
- Non-radioactive
light ballasts
- Suspect
or known PCB light ballasts are categorized as PCB Bulk Product Waste due to
PCBs in the tar-like potting material.
- Radioactive
small capacitors and light ballasts
- Contact
the Environmental and Waste Management
Services Division for additional details.
See Organic Peroxides
and Peroxide Forming Compounds

PPE is used routinely for a wide variety of operations. It includes disposable gloves,
boot protectors, and tyvek suits to name a few. The following is general guidance to
manage disposable PPE. If your specific PPE does not match this guidance please contact
your ECR or WMR for further instruction. It should be noted that some PPE such as
respirators may be managed in accordance with site specific health and safety plans, work
plans and standard operating procedures. These plans/procedures take precedence over this
guidance.
Non-Contaminated PPE (Non-RAD, Non-Hazardous, Non-Industrial) - Personnel Protective Equipment (tyvek suits, gloves, etc) that is not contaminated with
radioactive material, hazardous or industrial wastes, or OSHA regulated materials in
excess of permissible exposure limits (PELs) may be disposed of as municipal trash.
In some cases analytical tests are performed to prove certain PPE non-contaminated,
however, this is not necessary if sufficient generator knowledge and/or supporting data
exist.
RAD Contaminated PPE - All PPE contaminated with radioactive material shall be disposed of as compactible LLRW
in accordance with the SBMS
Radioactive
Waste Management subject area
Mixed Waste Contaminated PPE - All PPE contaminated with mixed waste shall be disposed of in accordance with the SBMS
Mixed Waste Management
subject area
Hazardous/Industrial Contaminated PPE - All PPE contaminated with hazardous or industrial waste shall be disposed of in
accordance with the SBMS
Hazardous
Waste Management subject area. This includes PPE contaminated in excess of OSHA
permissible exposure limits.

A recyclable material; dispose of in one of the blue plastic containers with the Town
of Brookhaven "Community Recycling" label.
Spent
stop bath and spent developing solution
must be handled as industrial wastes due to organic content as per the
requirements described in the Standards Based Management System (SBMS)
Industrial Waste Subject Area.
Spent
fixer and spent static rinse
are
RCRA hazardous liquid wastes due to silver content and are handled as hazardous
wastes in accordance with the SBMS
Hazardous Waste Management Subject Area. These wastes must be stored in
separate containers near their point of generation in the Satellite Accumulation
Area (SAA) until ready for transfer to the 90-day Hazardous Waste Storage Area.
Dynamic rinse
is a running rinse and may be acceptable for discharge directly to the sanitary
system based on completion of a Liquid Effluent Evaluation Form in accordance
with the SBMS
Liquid Effluents Subject Area and subsequent approval given by the Subject
Matter Expert from the Environmental and Waste Management Services Division

This guidance applies only to printed circuit boards and does not apply to
equipment containing printed circuit boards.
Most printed circuit boards are known to exhibit the characteristics of a hazardous
waste, because of the lead content of solder, and because of the possible toxic metal
content of other electrical components on the board1. However, if
printed circuit boards are collected for recycling, they do not need to be managed as a
hazardous waste.
Note: Boards that do not contain toxic metals1 or have attached
electrical components, such as the nickel/tin boards produced by the Printed Circuit Board
Shop in Instrumentation, are not RCRA Hazardous Waste. Recycling of these boards is
encouraged if the boards have scrap value; otherwise, these boards can be deposited into
the regular trash.
How Best to Manage Printed Circuit Boards
- Boards without electrical components - Bare printed
circuit boards (no electrical components) may be collected in metal chip bins for
recycling, including boards that contain lead solder. Collection for recycling eliminates
the need to manage them as hazardous waste. If they are not collected for recycling, then
they must be managed as hazardous waste unless they do not contain lead solder, in which
case they may be recycled or disposed in the regular trash.
- Boards with electrical components - Certain electrical
components on printed circuit boards contain toxic metals (mercury switches, mercury
relays, nickel-cadmium batteries and lithium batteries2). Boards with these
components must be managed as Hazardous Waste unless all toxic components are removed.
Removed toxic components must then be managed as hazardous waste in accordance with the
Hazardous Waste Management subject area. Boards with non-toxic components
(resistors, etc) may be managed like boards without components.
How Not to Manage Printed Circuit Boards
Since printed circuit boards
containing lead solder and/or toxic electrical components1 are a considered
hazardous waste, they must not be discarded into the regular trash.
Questions? Contact your
Environmental
Compliance Representative or Waste Management Representative.
1 The boards exhibit the RCRA Characteristic of Toxicity due to the
presence of one or more of the 8 RCRA toxic metals (Arsenic, Barium, Cadmium, Chromium,
Lead, Mercury, Selenium, and Silver).
2 Lithium is a hazardous waste because it exhibits the RCRA characteristic of
reactivity.

Place used cartridge in the package from the new cartridge. Follow any handling
precautions listed on the package. Call ext. 7238 (Procurement & Property Management-
"PPM") and request pick-up OR label the package "T-89 Shipping" and
place the package at the PPM dropoff/pickup area in your building.

Rad Contaminated or Activated
Containers
Rad contaminated or activated containers shall be accumulated,
stored, labeled and disposed of per requirements described in the BNL Standards Based
Management System subject area entitled
Radioactive Waste
Management.

Radioactive Sources
Radioactive source(s) receipt, use, storage, and disposal are
subject to the general requirements enumerated in the BNL Radiological Control Manual,
Chapter 4 entitled Radiological Records, Part 3 - Radioactive Source Controls and
Part 4 - Solid Radioactive Waste Management.
Prior to a disposal request, the owner, user, or custodian of a radioactive source
should determine if the source has any intrinsic value such that it may be re-usable by
another BNL organization within or outside department or division, or perhaps another
external facility affiliated with BNL or DOE. Consult with the BNL Radiological Controls
Division for potential transfer of source ownership and accountability. Consult with the
Safeguards and Security Divisions Isotopes and Special Materials if the source
contains an accountable nuclear material (e.g., plutonium, americium, curium, californium)
since these sources have intrinsic value and can be stored for future use.
If the source has been determined to be damaged, unusable, or has no value it may be
declared waste. First, the source custodian shall contact their Facility Support
Representative (FS Rep) to arrange for a radiological survey and leak check if applicable.
After radiological survey, the owner, user, or custodian shall package, mark, label, and
appropriately store waste in an approved area and complete a Radioactive Waste Control
Form
(RWCF) in consult with your FS Rep. Return completed RWCF to the
the Environmental and Waste Management
Services Division
Generator Services Section in Building 860.
Radioactive waste shall be identified, packaged, labeled, stored, and managed in
accordance with the requirements contained in the BNL Standards Based Management System
subject area entitled, Radioactive
Waste Management.

Scintillation cocktails not spiked with a radioactive isotope but
considered a hazardous (toluene or cumene based) or an industrial waste (Ultima gold type)
shall be identified, packaged, labeled, stored, and managed in accordance with the
requirements contained in the BNL Standards Based Management System (SBMS) subject area
entitled Hazardous Waste Management
Label the container with a red Hazardous Waste or a green Non-Hazardous Waste label, keep
the container closed. Complete a
Nonradioactive
Waste Control Form and move the container to the 90-Day
Accumulation Area. These cocktails are
usually in their original containers and if in good condition need no other packaging. Due to higher treatment and disposal costs, it is
recommended that cocktail solution in small vials and containers equaling a liter or less
be separated from the vial and placed in accepted waste packages. If the liquids cannot be separated from the
container due to time, cost, or other reason, refer to the packaging requirements given
below.
Scintillation cocktails spiked with a radioactive isotope or that
contain a radioactive analyte shall be identified, packaged, labeled, stored, and managed
in accordance with the requirements contained in the BNL Standards Based Management System
(SBMS) subject area entitled
Radioactive Waste
Management If hazardous constituents are
present in addition to radioactive constituents, treat the scintillation cocktail as mixed
waste [refer to the
Mixed Waste
Management subject area for more detail]. Due to higher treatment and disposal costs, it is
recommended that cocktail solution in small vials and containers equaling a liter or less
be separated from the vial and placed in accepted waste packages. If the liquids cannot be separated from the
container due to time, cost, or other reason, refer to the packaging requirements given
below.
Scintillation cocktails with short Half-Life Radioactive Wastes are
defined at BNL as wastes contaminated with radionuclides having a half-live
LESS THAN 90 DAYS (list of eligible isotopes).
Wastes contaminated with short half-life radionuclides may be treated by DECAY-IN-STORAGE (DIS) by storage
for a minimum of 10 HALF-LIVES. Decayed wastes may then be disposed by other
approved means depending on the other characteristics of the waste.
If time and space does not permit the proper draining of
scintillation cocktails the following containers shall be used:
- For large articles and
large volumes of scintillation cocktail vials and containers, use a 55-gallon, open-top,
steel drum (BNL Stock # K-60643)
- For smaller articles, use a
5-gallon poly bucket (BNL Stock #K-60632)
Note: For cocktails not separated from containers, Departments/Divisions maybe
charged back a possible 20% differential to cover additional costs incurred.

Wastes contaminated with Short Half-Life Radioactive Wastes may be managed as
Radioactive Waste (see the
Radioactive
Waste Management subject
area). Alternatively, they may be treated by Decay-in-Storage (DIS).
Short Half-Life Radioactive Wastes are defined at BNL as wastes contaminated with
radionuclides having a half-live LESS THAN 90 DAYS (list of eligible isotopes).
Wastes contaminated with short half-life radionuclides may be treated by DECAY-IN-STORAGE (DIS) by storage
for a minimum of 10 HALF-LIVES. Decayed wastes may then be disposed of via legally
authorized municipal, recycling, medical, or hazardous waste disposal methods, depending
on the other characteristics of the waste.
The following must be done to use DIS as a treatment method;
- Segregate the waste by isotope at the point of generation.
- Label the package with the isotope, activity, half-life, date of last addition of waste
and date of the ten half-life decay period.
- Store the waste for a minimum of 10 half-lives.
- At the end of the 10 half-life decay period and prior to disposal, the waste package
must surveyed for release from the radioactive area and must be indistinguishable from
background.
- All radioactive labels and markings must be removed prior to disposal as non-radioactive
waste.
- Retain a record of disposal, including the date of disposal, the date the waste was
placed in storage, the radionuclide disposed, the individual that disposed of the
material, and the details of the survey including the instrument used, the background dose
rate, and the dose rate measured at the surface of the container.

Waste solder from electronics repair and assembly operations is typically composed of
tin/lead or tin/silver solder. Waste solder should be collected in a container labeled
"Solder Scrap for Recycling". A single container located in the vicinity of the
soldering operations should suffice. When solder stations are cleaned, waste solder should
be emptied to the labeled container. When the container is full, it can be taken to
Central Shops Division, where it will be sent offsite for recycling. Contact Tom
Lambertson Ext. 3352 to make arrangements to bring it to Central Shops.
IF solder wastes are NOT recycled, then they must be managed as Hazardous Wastes due to
lead or silver content. A single Satellite
Accumulation Area located in the vicinity of the soldering operations should suffice.
The container must be labeled with a Hazardous Waste label, including
a description of the contents, and must be maintained closed except when adding or
removing waste. When full complete a
Non-radioactive
Waste Control Form and
move the container to the 90-Day Accumulation Area for pick up by Waste Management.

I. Disposal via the Environmental
and Waste Management Services Division
All solvents shall be accumulated, stored, labeled and disposed of as a hazardous waste
per the requirements described in the BNL Standards Based Management System subject area
entitled Hazardous Waste
Management.
Not all solvents are hazardous wastes, but should be managed as such unless a specific
determination has been made by the Environmental and Waste Management
Services Division (EWMSD) that your waste is non-hazardous. Contact
EWMSD for a determination or your
Environmental Compliance
Representative for help in identifying which streams may potentially be non-hazardous.
Unused chemicals that have not expired can be made available to the laboratory
community for use via the Chemical Management Systems "Chemical Exchange" program.
II. Solvent waste storage issues:
Flammable solvent waste (flashpoint £ 140 oF) is
incompatible with ammonium nitrate, chromic acid, hydrogen peroxide, nitric acid, sodium
peroxide, and the halogens and should not be stored with these materials.
Refer to the exhibit in the Hazardous Waste subject area titled
"Examples of Incompatible
Chemicals" for additional guidance regarding incompatible chemicals that should
not be stored together.
Questions? Contact your
Environmental
Compliance Representative or Waste Management Representative.

Disposal of rags contaminated with solvents depends on what solvents are on the
rag and whether the rag is dry.
Rags contaminated with the following Chlorinated Solvents must be
managed as Hazardous Waste
regardless of whether they are dry or not. (Tetrachloroethylene, trichloroethylene,
methylene chloride, 1,1,1-trichoroethane, carbon tetrachloride, all chlorinated
fluorocarbons...Freons, chlorobenzene, 1,1,2-trichloro-1,2,2-trifluoroethane,
ortho-dichlorobenzene, trichlorofluoromethane, and 1,1,2-trichloroethane). Package the
rags in a plastic bag or container, seal it and label it with a red/white Hazardous Waste
label with the description "Chlorinated Solvent Rags". Complete the
Nonradioactive
Waste Control Form and send to the the Environmental and
Waste Management Services Division.
Rags contaminated with the following Non-Chlorinated Solvents must
also be managed as
Hazardous Waste
regardless of whether they are dry. (Toluene, methyl ethyl ketone, carbon disulfide,
isobutanol, pyridine, benzene, 2-ethoxyethanol, 2-nitropropane, cresols, cresylic acid,
and nitrobenzene)
Rags contaminated with most other solvents (e.g., xylene, acetone, ethyl acetate, ethyl
benzene, ethyl ether, methyl isobutyl ketone, n-butyl alcohol, cyclohexanone, ethanol, and
methanol) can be disposed of in the trash or as Industrial Wastes IF THEY ARE DRY. NOTE: It is not permissible to purposefully air dry rags for disposal purposes.
Disposal as trash or industrial waste is intended for rags that have minimal solvent on
them and dry in the course of being used. If the rags are saturated and dripping they must
be disposed as ignitable hazardous waste.

Place used cartridge in the package from the new cartridge. Follow any handling
precautions listed on the package. Call ext. 7238 (Procurement & Property Management-
"PPM") and request pick-up OR label the package "T-89 Shipping" and
place the package at the PPM dropoff/pickup area in your building.

Handling of EXIT Signs Containing TRITIUM
In the mid 1980s, the Laboratory installed exit signs containing tritium at many
locations throughout the site. Under normal conditions, these signs pose no health impacts
to the occupants of the building even though they contain up to 25 curies of tritium.
These signs have a useful life of about 10 years and are now being cycled out of service.
While normally not an ES&H concern, there are some precautions regarding the
handling of these signs that building occupants and plant maintenance personnel should
know.
- When the signs are removed from service, they are to be returned to their
manufacturer for disposal.
- Tritium exit signs may not be disposed of in the sanitary trash or radioactive waste
disposal systems.
- A broken tritium exit sign has the potential to result in localized contamination
and potential radiation dose to people in the near vicinity of the breakage.
Anyone observing that a sign has fallen from a wall or ceiling mounting or has been
broken in any fashion should immediately contact a member of the Facilities Support staff
for your area or Bob Miltenberger, Ext. 2503 or pager 554-1967. If you don't know whom to
call or can't get a response, please call Ext. 911 or Ext. 2222 and report the breakage of
the sign to a member of the Safeguards and Security Division. The call will be treated as
a spill response and knowledgeable staff will be contacted to respond to the scene.
Unknown Chemical Substances
Unknowns must be characterized chemically and radiologically to be properly disposed.
Try to contact any and all personnel that may have knowledge of the material to record
'process knowledge'. Was the material radiologically contaminated (what isotope) or
activated? Is it ignitable, reactive, toxic or corrosive?
Without adequate process knowledge, unknowns will typically require gamma spectroscopy
and gross alpha/beta analysis to determine radiological characteristics. Contact Waste
Management or your Environmental Compliance Representative to determine chemical analysis that may be
required.
Label, label, label! That's the way to avoid creating or discovering unknowns.

Every effort should be made to find a use for unused lab chemicals prior to disposal.
List the chemicals on the BNL Chemical
Exchange to make them available to other BNL users. Contact your
Environmental Compliance
Representative to see if they known of other potential users on or off-site.
If you have exhausted reuse or recycling options, unused chemicals can be disposed
through the Waste Management Division. If you have a single bottle or just a few, process
them in accordance with the
Hazardous
Waste Management subject area. If you have numerous chemicals, contact
the Environmental and Waste
Management Services Division and request a Lab
Clean-Out.
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Last Modified: April 2, 2008 Please forward all questions about this site to:
Mary Daum
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