Valence and Chemical Determination of Li-Battery Using EELS
Frederic Cosandey
Department of Materials Science & Engineering,
Rutgers University
Piscataway, NJ
08854.
Electron Energy Loss Spectroscopy (EELS) is a powerful
technique for studying Li-Ion battery materials as Li distribution in the
electrode material can be mapped with nanometer scale resolution. In addition,
charge transfer during lithiation and delithiation processes can be determined
from the relative intensities of L3 and L2 lines of the transition metal (Fe, Mn,
Ni..). In this talk, the basic EELS technique will be reviewed and recent
results obtained on nanocomposite electrodes will be presented. In addition, the
chemical state of Li in compounds such as LiF, Li2CO3 can be determined form the
Li-K edge fine structure. Determination of Li compounds can be obtained by EELS
from comparison with known standards.