Radiation Chemistry of Ionic Liquids: Reactivity of Primary Species

James F. Wishart

In "Ionic Liquids as Green Solvents: Progress and Prospects" Rogers, R. D. and Seddon, K. R. , Eds.; ACS Symp. Ser. 856, Ch. 31, pp. 381-395, American Chemical Society, Washington, DC, 2003. (ISBN 0-84123-856-1) [Information about the book]

Abstract:

An understanding of the radiation chemistry of ionic liquids is important for development of their applications in radioactive material processing and for the application of pulse radiolysis techniques to the general study of chemical reactivity in ionic liquids. The distribution of primary radiolytic species and their reactivities determine the yields of ultimate products and the radiation stability of a particular ionic liquid. This chapter introduces some principles of radiation chemistry and the techniques used to perform radiolysis experiments. Kinetic studies of primary products and their reactions on short time scales are described and future challenges in ionic liquid radiation chemistry are outlined.