National Synchrotron Light Source Lunch Time Seminar

"Magnetic Field Induced Color Change in a-Fe203 Single Crystals"

Presented by Jan Musfeldt, Department of Chemistry, University of Tennessee Knoxville, TN

Friday, March 23, 2012, 12:00 pm — Seminar Room, Bldg. 725

We investigated the magneto-optical properties of a-Fe203 in order to understand the interplay between charge and magnetism in a model transition metal oxide. We discovered that hematite appears more red in applied magnetic field than in zero field conditions, an effect that is amplified by the presence of the spin flop transition. Analysis of the exciton pattern on the edge of the d-d color band reveals C2/c monoclinic symmetry in the high field phase. These findings advance our understanding of magnetoelectric coupling away from the static limit and motivate spectroscopic work on other iron-based materials under extreme conditions.

Hosted by: Elio Vescovo

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