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Electron- and Photo-Induced Processes

2022

  • Bird, M. J., Miller, J. R. “Effects of Electrolyte on Redox Potentials” Redox Chemistry - From Molecules to Energy Storage, IntechOpen 2022 ISBN: 978-1-80355-537-9
  • Grills, D. C.; Lymar, S. V. “Solvated Electron in Acetonitrile: Radiation Yield, Absorption Spectrum, and Equilibrium between Cavity- and Solvent-Localized States” J. Phys. Chem. B 2022, 126, 262-269. DOI: 10.1021/acs.jpcb.1c08946
  • González-López, L.; Kearney, L.; Janke, C. J.; Wishart, J.; Kanbargi, N.; Al-Sheikhly, M., On the Mechanism of the Steady-State Gamma Radiolysis-Induced Scissions of the Phenyl-Vinyl Polyester-Based Resins. Front. Chem. 2022, 9, 803347. DOI: 10.3389/fchem.2021.803347

2021

  • Cook, A. R. “Sub-picosecond Production of Solute Radical Cations in Tetrahydrofuran after Radiolysis” J. Phys. Chem. A, 2021, 125(47):10189-10197
    DOI: 10.1021/acs.jpca.1c08568
  • Celis Barros, C.; Pilgrim, C. D.; Cook, A. R.; Mezyk, S. P.; Grimes, T. S.; Horne, G. P. “Influence of Uranyl Complexation on the Reaction Kinetics of the Dodecane Radical Cation with Used Nuclear Fuel Extraction Ligands (TBP, DEHBA, and DEHiBA)” Phys. Chem. Chem. Phys. 2021, 23, 24589-24597. DOI: 10.1039/D1CP03797H
  • Yan, J.; Wilson, R. W.; Buck, J. T.; Grills, D. C.; Reinheimer, E. W.; Mani, T., IR linewidth and intensity amplifications of nitrile vibrations report nuclear-electronic couplings and associated structural heterogeneity in radical anions. Chem. Sci. 2021, 12, 12107-12117. Designated as an Edge Article. DOI: 10.1039/d1sc03455c
  • Toigawa, T.; Peterman, D. R.; Meeker, D. S.; Grimes, T. S.; Zalupski, P. R.; Mezyk, S. P.; Cook, A. R.; Yamashita, S.; Kumagai, Y.; Matsumura, T.; et al. "Radiation-induced effects on the extraction properties of hexa-n-octylnitrilo-triacetamide (HONTA) complexes of americium and europium" Phys. Chem. Chem. Phys. 2021, 23, 1343-1351. DOI:10.1039/D0CP05720G
  • Horne, G. P.; Grimes, T. S.; Zalupski, P. R.; Meeker, D. S.; Albrecht-Schönzart, T. E.; Cook, A. R.; Mezyk, S. P. "Curium(III) radiation-induced reaction kinetics in aqueous media" Dalton Trans. 2021, 50, 10853-10859. DOI:10.1039/D1DT01268A
  • Wishart, J. F.; Wang, F., Radiolysis of ionic liquids and molten salts. L’Actualité Chimique (Journal of the French Chemical Society), 2021, 460-461, 106-111 (in English). URL: https://new.societechimiquedefrance.fr/numero/la-radiolyse-des-liquides-ioniques-et-des-sels-fondus-defis-et-reussites-dans-le-domaine-de-lenergie-p106-n460-461/
  • Iwamatsu, K., Introduction of radiation chemistry experimental facility at Brookhaven National Laboratory. Houshasen-Kagaku (Biannual Journal of the Japanese Society of Radiation Chemistry) 2021, 111, 53-57 (in Japanese).

2020

  • Horne, G. P.; Zarzana, C. A.; Rae, C.; Cook, A. R.; Mezyk, S. P.; Zalupski, P. R.; Wilden, A.; Mincher, B. J. “Does Addition of 1-Octanol as a Phase Modifier Provide Radical Scavenging Radioprotection for N,N,N′,N′-Tetraoctyldiglycolamide (TODGA)?” Phys. Chem. Chem. Phys. 2020, 22, 24978-24985. DOI: 10.1039/D0CP04310A
  • Takeda, N.; Miller, J. R. "Inverted Region in Bimolecular Electron Transfer in Solution Enabled by Delocalization", J. Am. Chem. Soc., 2020, 142, 17997-18004 DOI:10.1021/jacs.0c04780.
  • Schatzman, S. S.; Peterson, R. L.; Teka, M.; He, B.; Cabelli, D. E.; Cormack, B. P.; Culotta, V. C.; “Copper-only superoxide dismutase enzymes and iron starvation stress in Candida fungal pathogens” J Biol. Chem. 2020, 295(2):570-583. DOI:10.1074/jbc.RA119.011084
  • Cook, A.; Girimonti, G.; Sreearunothai, P.; Asaoka, S.; Miller, J.; “Dynamic broadening alters triplet extinction coefficients in fluorene oligomers and polymers” J. Chem. Phys. 2020 152, 024901. DOI:10.1063/1.5132798
  • Boudreau, A. M.; Wilson, R. W.; Yang, M.; Grills, D. C.; Mani, T.; “Vibrational Spectroscopy Reveals Effects of Electron Push–Pull and Solvent Polarity on Electron Delocalization in Radical Anions of Donor–Acceptor Compounds” J. Phys. Chem. B 2020, 124 (8), 1543-1549. DOI:10.1021/acs.jpcb.9b11747
  • Dispenza, C.; Sabatino, M. A.; Grimaldi, N.; Dahlgren, B.; Al-Sheikhly, M.; Wishart, J. F.; Tsinas, Z.; Poster, D. L.; Jonsson, M.; “On the nature of macroradicals formed upon radiolysis of aqueous poly(N-vinylpyrrolidone) solutions” Rad. Phys. Chem., 174, 2020, 108900. DOI:10.1016/j.radphyschem.2020.108900
  • Bird, M. J.; Pearson, M. A.; Asaoka, S.; Miller, J. R.; “General Method for Determining Redox Potentials without Electrolyte” J. Phys. Chem. A 2020, 124 (26), 5487-5495. DOI:10.1021/acs.jpca.0c02948
  • Aubry, T. J.; Winchell, K. J.; Salamat, C. Z.; Basile, V. M.; Lindemuth, J. R.; Stauber, J. M.; Axtell, J. C.; Kubena, R. M.; Phan, M. D.; Bird, M. J.; Spokoyny, A. M.; Tolbert, S. H.; Schwartz, B. J.; “Tunable Dopants with Intrinsic Counterion Separation Reveal the Effects of Electron Affinity on Dopant Intercalation and Free Carrier Production in Sequentially Doped Conjugated Polymer Films.” Adv. Funct. Mater. 2020, 30, 2001800. DOI:10.1002/adfm.202001800
  • Bird, M. J.; Cook, A. R.; Zamadar, M.; Asaoka, S.; Miller, J. R.; “Pushing the limits of the electrochemical window with pulse radiolysis in chloroform” Phys. Chem. Chem. Phys., 2020,22, 14660-14670. DOI:10.1039/D0CP01948H
  • Horne, G. P.; Zarzana, C. A.; Rae, C.; Cook, A. R.; Mezyk, S. P.; Zalupski, P. R.; Wilden, A.; Mincher, B. J. "Does addition of 1-octanol as a phase modifier provide radical scavenging radioprotection for N,N,N′, N′-tetraoctyldiglycolamide (TODGA)?" Physical Chemistry Chemical Physics 2020, 22, 24978-24985. DOI:10.1039/D0CP04310A
  • Steinrück, H.-G.; Cao, C.; Lukatskaya, M.; Takacs, C.; Wan, G.; Mackanic, D.; Tsao, Y.; Zhao, J.; Helms, B.; Xu, K.; Borodin, O.; Wishart, J. F.; Toney, M., Interfacial Speciation Determines Interfacial Chemistry: X-ray-Induced Lithium Fluoride Formation from Water-in-salt Electrolytes on Solid Surfaces. Chem. Int. Ed. 2020, 59, 23180-23187. DOI:10.1002/anie.202007745
  • Hemraj-Benny, T.; Lall-Ramnarine, S. I.; Suarez, S.; Paterno, D.; Ramdihal, J. D.; Sumner, R.; Urena, K.; Wishart, J. F., A Comparative Study of Imidazolium-Based Ionic Liquid-Single-Walled Carbon Nanotube Composites with Enhanced Conductivity Properties for Supercapacitor Applications. ECS Trans. 2020, 98, 73-87. DOI: 10.1149/09810.0073ecst

2019

  • Holroyd, R. A.; Miller, J. R. "Rate versus Free Energy Change for Attaching Highly Mobile Electrons to Molecules in Nonpolar Liquids", J. Phys. Chem. B, 2019, 123, 9206-9211 DOI:10.1021/acs.jpcb.9b07845.
  • Ryerson, J. L.; Zaykov, A.; Suarez, L. E. A.; Havenith, R. W. A.; Stepp, B. R.; Dron, P. I.; Kaleta, J.; Akdag, A.; Teat, S. J.; Magnera, T. F.; Miller, J. R.; Havlas, Z.; Broer, R.; Faraji, S.; Michl, J.; Johnson, J. C. "Structure and photophysics of indigoids for singlet fission: Cibalackrot", J. Chem. Phys., 2019, 151  DOI:10.1063/1.5121863.
  • Cook, A. R.; Asaoka, S.; Li, X.; Miller, J. R.; “ Electron Transport with Mobility, μ > 86 cm2/(V s), in a 74 nm Long Polyfluorene” J. Phys. Chem. Lett. 2019, 10 (2), 171-175  DOI: 10.1021/acs.jpclett.8b03185
  • Burke, J. H.; Bird, M. J.; “Energetics and Escape of Interchain‐Delocalized Ion Pairs in Nonpolar Media” Adv. Mater. 2019, 31, 1806863. DOI: 10.1002/adma.201806863
  • Lymar, S. V.; Manbeck, G. F.; Polyansky, D. E.; “ Hydrogen bonding between hydroxylic donors and MLCT-excited Ru(bpy)2(bpz)2+ complex: implications for photoinduced electron–proton transfer” Chem. Commun., 2019, 55, 5870-5873 DOI: 10.1039/C9CC01896D
  • Horne, G.P.' Kiddle, J.J.; Zarzana, C.A.; Rae, C.; Peller, J.R.; Cook, A.R.; Mezyk, S.P.; Mincher, B.J.; “31P NMR study of the activated radioprotection mechanism of octylphenyl-N,N-diisobutylcarbamoylmethyl phosphine oxide (CMPO) and analogues” Dalton Trans., 2019, 48, 11547-11555 DOI: 10.1039/C9DT01950B
  • Carnahan, S. L.; Venkatesh, A.; Perras, F. A.; Wishart, J. F.; Rossini, A. J.; “High-Field Magic Angle Spinning Dynamic Nuclear Polarization Using Radicals Created by γ-Irradiation” J. Phys. Chem. Lett. 2019 10 (17), 4770-4776 DOI: 10.1021/acs.jpclett.9b01655
  • Zeng, H. J.; Johnson, M. A.; Ramdihal, J. D.; Sumner, R. A.; Rodriguez, C.; Lall-Ramnarine, S. I.; Wishart, J. F.; “Spectroscopic Assessment of Intra- and Intermolecular Hydrogen Bonding in Ether-Functionalized Imidazolium Ionic Liquids” J. Phys. Chem. A 2019 123 (39), 8370-8376 DOI: 10.1021/acs.jpca.9b04345
  • Zhao, M.; Wu, B.; Lall-Ramnarine, S. I.; Ramdihal, J. D.; Papacostas, K. A.; Fernandez, E. D.; Sumner, R. A.; Margulis, C. J.; Wishart, J. F.; and Edward W. Castner Jr., E. W.; “ Structural analysis of ionic liquids with symmetric and asymmetric fluorinated anions” J. Chem. Phys. 2019, 151, 074504 DOI: 10.1063/1.5111643
  • Miller, J. R.; Cook, A. R.; Šimková, L.; Pospíšil, L.; Ludvík, J.; and Michl, J.; “The Impact of Huge Structural Changes on Electron Transfer and Measurement of Redox Potentials: Reduction of ortho-12-Carborane” J. Phys. Chem. B 2019, 123 (45), 9668-9676  DOI: 10.1021/acs.jpcb.9b08151

2018

  • Wang, L.; Yan, D.; Shaffer, D. W.; Ye, X.; Layne, B. L.; Concepcion, J. J.; Liu, M.; and Nam. C-Y.; “Improved Stability and Performance of Visible Photoelectrochemical Water Splitting on Solution-Processed Organic Semiconductor Thin Films by Ultrathin Metal Oxide Passivation”, Chemistry of Materials 2018, 30 (2), 324-335. DOI: 10.1021/acs.chemmater.7b02889
  • Huang, H.-T.; Dillon, S.; Ryan, K.C.; Campecino, J.O.; Watkins, O.E.; Cabelli, D.E.; Brunold, T.C.; Maroney, M.J. “The Role of Mixed Amine/Amide Ligation in Nickel Superoxide Dismutase” Inorg. Chem. 2018, 7 (20), 12521-12535. DOI: 10.1021/acs.inorgchem.8b01499
  • Cabelli, D.E.; “Redox activity goes organic.” Nature Chem. 10, 2018, 1173–1175. DOI: 10.1038/s41557-018-0180-y
  • Lymar, S. V.; Ertema. M. Z.; Polyansky. D. E.; “Solvent-dependent transition from concerted electron–proton to proton transfer in photoinduced reactions between phenols and polypyridine Ru complexes with proton-accepting sites” Dalton Trans., 2018,47, 15917-15928. DOI: 10.1039/C8DT03858A
  • Chen, J. G.; Crooks, R. M.; Seefeldt, L. C.; Bren, K. L.; Bullock, R. M.; Darensbourg, M. Y.; Holland, P. L.; Hoffman, B.; Janik, M. J.; Jones, A. K.; Kanatzidis, M. G.; King, P.; Lancaster, K. M.; Lymar, S. V.; Pfromm, P.; Schneider, W. F.; Schrock, R. R. "Beyond Fossil Fuel–Driven Nitrogen Transformations" Science 2018, 360. DOI:10.1126/science.aar6611
  • Grills, D. C.; Lymar, S. V. Radiolytic Formation of the Carbon Dioxide Radical Anion in Acetonitrile Revealed by Transient IR Spectroscopy Phys. Chem. Chem. Phys. 2018, 20, 10011-10017. DOI:10.1039/c8cp00977e
  • Cook, A. R.; Valášek, M.; Funston, A. M.; Poliakov, P.; Michl, J.; Miller, J. R. "p-Carborane Conjugation in Radical Anions of Cage–Cage and Cage–Phenyl Compounds" J. Phys. Chem. A 2018, 122, 798-810. DOI:10.1021/acs.jpca.7b10885
  • Wu, B.; Liang, M.; Zmich, N.; Hatcher, J.; Lall-Ramnarine, S. I.; Wishart, J. F.; Maroncelli, M.; Castner, E. W. "Photoinduced Bimolecular Electron Transfer in Ionic Liquids: Cationic Electron Donors" J. Phys. Chem. B 2018, 122, 2379-2388. DOI:10.1021/acs.jpcb.7b12542
  • Das, L.; Kumar, R.; Maity, D. K.; Adhikari, S.; Dhiman, S. B.; Wishart, J. F. "Pulse Radiolysis and Computational Studies on a Pyrrolidinium Dicyanamide Ionic Liquid: Detection of the Dimer Radical Anion" J. Phys. Chem. A 2018, 122, 3148-3155. DOI:10.1021/acs.jpca.8b00978
  • Kakinuma, S.; Ramati, S.; Wishart, J. F.; Shirota, H., Effects of aromaticity in cations and their functional groups on the temperature dependence of low-frequency spectrum. J. Chem. Phys. 2018, 148, 193805. DOI:10.1063/1.5010066
  • Abbott, A.; Abe, H.; Aldous, L.; Atkin, R.; Bendova, M.; Busato, M.; Canongia Lopes, J. N.; Costa Gomes, M.; Cross, B.; Dietz, C.; Everts, J.; Firestone, M.; Gardas, R.; Gras, M.; Greaves, T.; Halstead, S.; Hardacre, C.; Harper, J.; Holbrey, J.; Jacquemin, J.; Jessop, P.; MacFarlane, D.; Maier, F.; Medhi, H.; Mezger, M.; Padua, A.; Perkin, S.; Reid, J.; Saha, S.; Slattery, J. M.; Thomas, M. L.; Tiwari, S.; Tsuzuki, S.; Uralcan, B.; Watanabe, M.; Wishart, J.; Youngs, T. "Phase Behaviour and Thermodynamics: General Discussion" Faraday Discuss. 2018, 206, 113-139. DOI:10.1039/c7fd90091k
  • Abbott, A.; Aldous, L.; Borisenko, N.; Coles, S.; Fontaine, O.; Garcia, J. D. G.; Gardas, R.; Hammond, O.; Hardwick, L. J.; Haumesser, P. H.; Hausen, F.; Horwood, C.; Jacquemin, J.; Jones, R.; Jonsson, E.; Lahiri, A.; MacFarlane, D.; Marlair, G.; May, B.; Medhi, H.; Paschoal, V. H.; Reid, J.; Schoetz, T.; Tamura, K.; Thomas, M. L.; Tiwari, S.; Uralcan, B.; van den Bruinhorst, A.; Watanabe, M.; Wishart, J. "Electrochemistry: General Discussion" Faraday Discuss. 2018, 206, 405-426. DOI:10.1039/c7fd90093g
  • Abbott, A.; Addicoat, M.; Aldous, L.; Bhuin, R. G.; Borisenko, N.; Canongia Lopes, J. N.; Clark, R.; Coles, S.; Costa Gomes, M.; Cross, B.; Everts, J.; Firestone, M.; Gardas, R.; Gras, M.; Halstead, S.; Hardacre, C.; Holbrey, J.; Itoh, T.; Ivanistsev, V.; Jacquemin, J.; Jessop, P.; Jones, R.; Kirchner, B.; Li, S. C.; Lynden-Bell, R.; MacFarlane, D.; Maier, F.; Mezger, M.; Padua, A.; Pavel, O. D.; Perkin, S.; Purcell, S.; Rutland, M.; Slattery, J. M.; Suzer, S.; Tamura, K.; Thomas, M. L.; Tiwari, S.; Tsuzuki, S.; Uralcan, B.; Wallace, W.; Watanabe, M.; Wishart, J. "Ionic Liquids at Interfaces: General Discussion" Faraday Discuss. 2018, 206, 549-586. DOI:10.1039/c7fd90094e
  • Addicoat, M.; Atkin, R.; Canongia Lopes, J. N.; Costa Gomes, M.; Firestone, M.; Gardas, R.; Halstead, S.; Hardacre, C.; Hardwick, L. J.; Holbrey, J.; Hunt, P.; Ivanistsev, V.; Jacquemin, J.; Jones, R.; Kirchner, B.; Lynden-Bell, R.; MacFarlane, D.; Marlair, G.; Medhi, H.; Mezger, M.; Padua, A.; Pantenburg, I.; Perkin, S.; Reid, J.; Rutland, M.; Saha, S.; Shimizu, K.; Slattery, J. M.; Swadzba-Kwasny, M.; Tiwari, S.; Tsuzuki, S.; Uralcan, B.; van den Bruinhorst, A.; Watanabe, M.; Wishart, J. "Structure and Dynamics of Ionic Liquids: General Discussion" Faraday Discuss. 2018, 206, 291-337. DOI:10.1039/c7fd90092a
  • Mani, T.; Grills, D. C. "Nitrile Vibration Reports Induced Electric Field and Delocalization of Electron in Charge-Transfer State of Aryl Nitriles" J. Phys. Chem. A 2018, 122, 7293-7300. DOI:10.1021/acs.jpca.8b08025

2017

  • Bird, M. J.; Bakalis, J.; Asaoka, S.; Sirringhaus, H.; Miller, J. R. Fast Holes, Slow Electrons, and Medium Control of Polaron Size and Mobility in the Da Polymer F8bt, J. Phys. Chem. C 2017, 121, 15597-15609.  DOI:10.1021/acs.jpcc.7b04602.
  • Chen, H. C.; Sreearunothai, P.; Cook, A. R.; Asaoka, S.; Wu, Q.; Miller, J. R. Chain Length Dependence of Energies of Electron and Triplet Polarons in Oligofluorenes, J. Phys. Chem. C2017, 121, 5959-5967. DOI:10.1021/acs.jpcc.7b00099.
  • Wishart, J. F. Radiation and Radical Chemistry of Ionic Liquids for Energy Applications. In Ionic Liquids: Current State and Future Directions, Shiflett, M. B.; Scurto, A. M., Eds. American Chemical Society: 2017; Vol. 1250, pp 251-272. DOI:10.1021/bk-2017-1250.ch011
  • Chen, H.-C.; Cook, A. R.; Asaoka, S.; Boschen, J. S.; Windus, T. L.; Miller, J. R. "Escape of Anions from Geminate Recombination in THF Due to Charge Delocalization" Phys. Chem. Chem. Phys. 2017, 19, 32272-32285. DOI:10.1039/C7CP05880B
  • Lall-Ramnarine, S. I.; Zhao, M.; Rodriguez, C.; Fernandez, R.; Zmich, N.; Fernandez, E. D.; Dhiman, S. B.; Castner, E. W.; Wishart, J. F. "Connecting Structural and Transport Properties of Ionic Liquids with Cationic Oligoether Chains" J. Electrochem. Soc. 2017, 164, H5247-H5262. DOI:10.1149/2.0371708jes
  • Lall-Ramnarine, S. I.; Suarez, S. N.; Fernandez, E. D.; Rodriguez, C.; Wei, S. J.; Gobet, M.; Jayakody, J. R. P.; Dhiman, S. B.; Wishart, J. F. "Exploring the Use of Ionic Liquid Mixtures to Enhance the Performance of Dicationic Ionic Liquids" J. Electrochem. Soc. 2017, 164, H5150-H5159. DOI:10.1149/2.0271708jes
  • Pilar, K.; Rua, A.; Suarez, S. N.; Mallia, C.; Lai, S.; Jayakody, J. R. P.; Hatcher, J. L.; Wishart, J. F.; Greenbaum, S. "Investigation of Dynamics in BMIM TFSA Ionic Liquid through Variable Temperature and Pressure NMR Relaxometry and Diffusometry" J. Electrochem. Soc. 2017, 164, H5189-H5196. DOI:10.1149/2.0301708jes
  • Mani, T.; Grills, D. C. "Probing Intermolecular Electron Delocalization in Dimer Radical Anions by Vibrational Spectroscopy" J. Phys. Chem. B 2017, 121, 7327-7335. DOI:10.1021/acs.jpcb.7b02559
  • Lymar, S. V.; Ertem, M. Z.; Lewandowska-Andralojc, A.; Polyansky, D. E. "Role of Hydrogen Bonding in Photoinduced Electron–Proton Transfer from Phenols to a Polypyridine Ru Complex with a Proton-Accepting Ligand" J. Phys. Chem. Lett. 2017, 8, 4043-4048. DOI:10.1021/acs.jpclett.7b01614
  •  Sitaputra, W.; Stacchiola, D.; Wishart, J. F.; Wang, F.; Sadowski, J. T. "In Situ Probing of Ion Ordering at an Electrified Ionic Liquid/Au Interface" Adv. Mater. 2017, 29, 1606357. DOI:10.1002/adma.201606357
  • Bird, M. J.; Iyoda, T.; Bonura, N.; Bakalis, J.; Ledbetter, A. J.; Miller, J. R. "Effects of Electrolytes on Redox Potentials through Ion Pairing" J. Electroanal. Chem. 2017, 804, 107-115. DOI:10.1016/j.jelechem.2017.09.030

2016

  • Wu, Q.; Zaikowski, L.; Kaur, P.; Asaoka, S.; Gelfond, C.; Miller, J. R. Multiply Reduced Oligofluorenes: Their Nature and Pairing with THF-Solvated Sodium Ions, J. Phys. Chem.  C 2016, 120, 16489-16499.  DOI:10.1021/acs.jpcc.6b05115
  • Lall-Ramnarine, S. I.; Fernandez, E. D.; Rodriguez, C.; Wei, S. J.; Dhiman, S. B.; Wishart, J. F. "Transport Properties of Ionic Liquid Mixtures Containing Heterodications" ECS Trans. 2016, 75, 555-565. DOI:10.1149/07515.0555ecst
  • Lall-Ramnarine, S. I.; Rodriguez, C.; Fernandez, R.; Zmich, N.; Fernandez, E. D.; Dhiman, S. B.; Wishart, J. F. "The Effect of Lengthening Cation Ether Tails on Ionic Liquid Properties" ECS Trans. 2016, 75, 215-232. DOI:10.1149/07515.0215ecst
  • Hack, J.; Grills, D. C.; Miller, J. R.; Mani, T. "Identification of Ion-Pair Structures in Solution by Vibrational Stark Effects" J. Phys. Chem. B 2016, 120, 1149-1157. DOI:10.1021/acs.jpcb.5b11893
  • Alexandrou, K.; Masurkar, A.; Edrees, H.; Wishart, J. F.; Hao, Y. F.; Petrone, N.; Hone, J.; Kymissis, I. Improving the radiation hardness of graphene field effect transistors. Appl. Phys. Lett. 2016, 109, 153108. DOI:10.1063/1.4963782
  • Mezyk, S. P.; Horne, G. P.; Mincher, B. J.; Zalupski, P. R.; Cook, A. R.; Wishart, J. F. The Chemistry of Separations Ligand Degradation by Organic Radical Cations. Procedia Chem. 2016, 21, 61-65. DOI:10.1016/j.proche.2016.10.009
  • Peterson, R. L.; Galaleldeen, A.; Villarreal, J.; Taylor, A. B.; Cabelli, D. E.; Hart, P. J.; Culotta, V. C. The Phylogeny and Active Site Design of Eukaryotic Copper-only Superoxide Dismutases. J. Biol. Chem. 2016, 291, 20911-20923. DOI:10.1074/jbc.M116.748251
  • Mezyk, S. P.; Mincher, B. J.; Dhiman, S. B.; Layne, B.; Wishart, J. F. The role of organic solvent radical cations in separations ligand degradation. J. Radioanal. Nucl. Chem. 2016, 307, 2445-2449. DOI:10.1007/s10967-015-4582-7

2015

  • Mani, T.; Grills, D. C.; Newton, M. D.; Miller, J. R. Electron Localization of Anions Probed by Nitrile Vibrations, J. Am. Chem. Soc. 2015, 137, 10979-10991. DOI:10.1021/jacs.5b04648
  • Campecino, J. O.; Dudycz, L. W.; Tumelty, D.; Berg, V.; Cabelli, D. E.; Maroney, M. J. A Semisynthetic Strategy Leads to Alteration of the Backbone Amidate Ligand in the NiSOD Active Site. J. Am. Chem. Soc. 2015, 137, 9044-9052. DOI:10.1021/jacs.5b03629
  • Sanders, S. N.; Kumarasamy, E.; Pun, A. B.; Trinh, M. T.; Choi, B.; Xia, J. L.; Taffet, E. J.; Low, J. Z.; Miller, J. R.; Roy, X.; Zhu, X. Y.; Steigerwald, M. L.; Sfeir, M. Y.; Campos, L. M. Quantitative Intramolecular Singlet Fission in Bipentacenes, J. Am. Chem. Soc. 2015, 137, 8965-8972. DOI:10.1021/jacs.5b04986
  • Busby, E.; Xia, J. L.; Wu, Q.; Low, J. Z.; Song, R.; Miller, J. R.; Zhu, X. Y.; Campos, L. M.; Sfeir, M. Y. A Design Strategy for Intramolecular Singlet Fission Mediated by Charge-Transfer States in Donor-Acceptor Organic Materials, Nature Materials2015, 14, 426-433.  DOI:10.1038/nmat4175.
  • Bird, M.; Mauro, G.; Zaikowski, L.; Li, X.; Reid, O.; Karten, B.; Asaoka, S.; Chen, H. C.; Cook, A. R.; Rumbles, G.; Miller, J. R. Singlet, Triplet, Electron and Hole Transport Along Single Polymer Chains, In Physical Chemistry of Interfaces and Nanomaterials Xiv; Hayes, S. C., Bittner, E. R., Eds. 2015; Vol. 9549.   DOI:10.1117/12.2188873
  • Shkrob, I. A.; Wishart, J. F.; Abraham, D. P. "What Makes Fluoroethylene Carbonate Different?" J. Phys. Chem. C 2015, 119, 14954-14964. DOI:10.1021/acs.jpcc.5b03591
  • Pratt, A. J.; DiDonato, M.; Shin, D. S.; Cabelli, D. E.; Bruns, C. K.; Belzer, C. A.; Gorringe, A. R.; Langford, P. R.; Tabatabai, L. B.; Kroll, J. S.; Tainer, J. A.; Getzoff, E. D. Structural, Functional, and Immunogenic Insights on Cu,Zn Superoxide Dismutase Pathogenic Virulence Factors from Neisseria meningitidis and Brucella abortus. J. Bacteriol. 2015, 197, 3834-3847. DOI:10.1128/jb.00343-15
  • Hunter, G. J.; Trinh, C. H.; Bonetta, R.; Stewart, E. E.; Cabelli, D. E.; Hunter, T. The structure of the Caenorhabditis elegans manganese superoxide dismutase MnSOD-3-azide complex. Protein Sci. 2015, 24, 1777-1788. DOI:10.1002/pro.2768
  • Devine, J. A.; Labib, M.; Harries, M. E.; Abdel Malak Rached, R.; Issa, J.; Wishart, J. F.; Castner, Jr., E. W. "Electron Transfer Dynamics for a Donor-Bridge-Acceptor Complex in Ionic Liquids" J. Phys. Chem. B 2015, 119, 11336-11345. DOI:10.1021/acs.jpcb.5b03320
  • Grills, D. C.; Jaime A. Farrington; Layne, B. H.; Preses, J. M.; Bernstein, H. J.; Wishart, J. F.,Development of nanosecond time-resolved infrared detection at the LEAF pulse radiolysisfacility. Rev. Sci. Instrum. 2015, 86, 044102. DOI:10.1063/1.4918728
  • Armstrong, D. A.; Huie, R. E.; Lymar, S.; Koppenol, W. H.; Merényi, G.; Neta, P.; Ruscic, B.; Stanbury, D. M.; Steenken, S.; Wardman, P. "Standard Electrode Potentials Involving Radicals in Aqueous Solution: Inorganic Radicals (IUPAC Technical Report)" Pure Appl. Chem. 87, 1139. DOI:10.1515/pac-2014-0502
  • Mani, T.; Grills, D. C.; Miller, J. R. "Vibrational Stark Effects to Identify Ion Pairing and Determine Reduction Potentials in Electrolyte-Free Environments" J. Am. Chem. Soc. 2015, 137, 1136-1140. DOI:10.1021/ja512302c
  • Busby, E.; Xia, J.; Wu, Q.; Low, J. Z.; Song, R.; Miller, J. R.; Zhu, X. Y.; Campos, Luis m.; Sfeir, M. Y. "A Design Strategy for Intramolecular Singlet Fission Mediated by Charge-Transfer States In donor–Acceptor Organic Materials" Nat. Mater. 2015, 14, 426-433. DOI:10.1038/nmat4175
  • Lall-Ramnarine, S. I.; Thomas, M. F.; Jalees, M.; Payen, F.; Boursiquot, S.; Ramati, S.; Ewko, D.; Zmich, N. V.; Wishart, J. F. "Probing the Physical Properties, Synthesis and Cellulose Dissolution Ability of Dialkyl Phosphate Ionic Liquids" Phosphorus, Sulfur, and Silicon and the Related Elements 2015, 190, 891-895. . DOI:10.1080/10426507.2014.985824
  • Hurst, J. K.; Roemeling, M. D.; Lymar, S. V. "Mechanistic Insight into Peroxydisulfate Reactivity: Oxidation of the cis,cis-[Ru(bpy)2(OH2)]2O4+ “Blue Dimer”" J. Phys. Che. Bm 2015, DOI:10.1021/acs.jpcb.5b00922
  • Zarzana, C. A.; Groenewold, G. S.; Mincher, B. J.; Mezyk, S. P.; Wilden, A.; Schmidt, H.;Modolo, G.; Wishart, J. F.; Cook, A. R., A comparison of the g-radiolysis of TODGA and T(EH)DGA using UHPLC-ESI-MS analysis. Solv. Extr. Ion Exch. 2015, 33, 431-447. DOI:10.1080/07366299.2015.1012885
  • Dassanayake, R. S.; Cabelli, D. E.; Brasch, N. E. Pulse radiolysis studies of the reactions of nitrogen dioxide with the vitamin B-12 complexes cob(II)alamin and nitrocobalamin. J. Inorg.Biochem. 2015, 142, 54-58. DOI: 10.1016/j.jinorgbio.2014.09.014
  • Dassanayake, R. S.; Shelley, J. T.; Cabelli, D. E.; Brasch, N. E. Pulse Radiolysis and Ultra-High-Performance Liquid Chromatography/High-Resolution Mass Spectrometry Studies on the Reactions of the Carbonate Radical with Vitamin B12 Derivatives. Chem. Eur. J. 2015, 21, 6409-6419. DOI:10.1002/chem.201406269
  • Pinto, A. F.; Romão, C. V.; Pinto, L. C.; Huber, H.; Saraiva, L. M.; Todorovic, S.; Cabelli, D.;Teixeira, M., Superoxide reduction by a superoxide reductase lacking the highly conserved lysineresidue. J. Biol. Inorg. Chem. 2015, 20, 155-164. DOI:10.1007/s00775-014-1222-6
  • Ryan, K. C.; Guce, A. I.; Johnson, O. E.; Brunold, T. C.; Cabelli, D. E.; Garman, S. C.; Maroney,M. J., Nickel Superoxide Dismutase: Structural and Functional Roles of His1 and its H-Bonding Network. Biochem. 2015, 54, 1016-1027. DOI:10.1021/bi501258u
  • Sea, K.; Sohn, S. H.; Durazo, A.; Sheng, Y.; Shaw, B. F.; Cao, X.; Taylor, A. B.; Whitson, L. J.;Holloway, S. P.; Hart, P. J.; Cabelli, D. E.; Gralla, E. B.; Valentine, J. S., Insights into the Role ofthe Unusual Disulfide Bond in Copper-Zinc Superoxide Dismutase. J. Biol. Chem. 2015, 290,2405-2418. DOI:10.1074/jbc.M114.588798
  • Musat, R. M.; Crowell, R. A.; Polyanskiy, D. E.; Thomas, M. F.; Wishart, J. F.; Katsumura, Y.; Takahashi, K., Ultrafast transient absorption spectrum of the room temperature Ionic liquid 1-hexyl-3-methylimidazolium bromide: Confounding effects of photo-degradation. Radiat. Phys. Chem. 2015, 117, 78-82. DOI:10.1016/j.radphyschem.2015.07.015
  • Suarez, S. N.; Rua, A.; Cuffari, D.; Pilar, K.; Hatcher, J. L.; Ramati, S.; Wishart, J. F., Do TFSA Anions Slither? Pressure Exposes the Role of TFSA Conformational Exchange in Self-Diffusion. J. Phys. Chem. B 2015, 119, 14756-14765. DOI:10.1021/acs.jpcb.5b08658
  • Shirota, H.; Matsuzaki, H.; Ramati, S.; Wishart, J. F., Effects of Aromaticity in Cations and Their Functional Groups on the Low-Frequency Spectra and Physical Properties of Ionic Liquids. J. Phys. Chem. B 2015, 119, 9173-9187. DOI:10.1021/jp509412z
  • Zaikowski, L.; Mauro, G.; Bird, M.; Karten, B.; Asaoka, S.; Wu, Q.; Cook, A. R.; Miller, J. R. Charge Transfer Fluorescence and 34 nm Exciton Diffusion Length in Polymers with Electron Acceptor End Traps. J. Phys. Chem. B 2015, 119, 7231-7241. DOI:10.1021/jp510095p
  • Li, X.; Bird, M.; Mauro, G.; Asaoka, S.; Cook, A. R.; Chen, H.-C.; Miller, J. R. Transport of Triplet Excitons along Continuous 100 nm Polyfluorene Chains. J. Phys. Chem. B 2015, 119, 7210-7218. DOI:10.1021/jp509396s

2014

  • Grills, D. C.; Farrington, J. A.; Layne, B. H.; Lymar, S. V.; Mello, B. A.; Preses, J. M.; Wishart, J. F. "Mechanism of the Formation of a Mn-Based CO2 Reduction Catalyst Revealed by Pulse Radiolysis with Time-Resolved Infrared Detection" J. Am. Chem. Soc. 2014, 136, 5563-5566. DOI:10.1021/ja501051s
  • Shaikh, N.; Valiev, M.; Lymar, S. V. "Decomposition of Amino Diazeniumdiolates (NONOates): Molecular Mechanisms" J. Inorg. Biochem. 2014, 141, 28-35. DOI:10.1016/j.jinorgbio.2014.08.008
  • Polyansky, D. E.; Hurst, J. K.; Lymar, S. V. "Application of Pulse Radiolysis to Mechanistic Investigations of Water Oxidation Catalysis" Eur. J. Inorg. Chem. 2014, 619-634. DOI:10.1002/ejic.201300753
  • Kottas, G. S.; Brotin, T.; Schwab, P. F. H.; Gala, K.; Havlas, Z.; Kirby, J. P.; Miller, J. R.; Michl, J. "Tetraarylcyclobutadienecyclopentadienylcobalt Complexes: Synthesis, Electronic Spectra, Magnetic Circular Dichroism, Linear Dichroism, and Td Dft Calculations" Organometallics 2014, 33, 3251-3264. DOI:10.1021/om400403j
  • Miller, J. R. "Electron Transfer Lower Tunnel Barriers" Nature Chemistry 2014, 6, 854-855. DOI:10.1038/nchem.2059
  • Cabelli, D. Probing Superoxide Dismutases through Radiation Chemistry. Israel J. Chem. 2014,54, 272-278. DOI: 10.1002/ijch.201300120
  • Sheng, Y.; Abreu, I. A.; Cabelli, D. E.; Maroney, M. J.; Miller, A.-F.; Teixeira, M.; Valentine, J.S. Superoxide Dismutases and Superoxide Reductases. Chem. Rev. 2014, 114, 3854-3918. DOI:10.1021/cr4005296
  • Gleason, J. E.; Galaleldeen, A.; Peterson, R. L.; Taylor, A. B.; Holloway, S. P.; Waninger-Saroni, J.; Cormack, B. P.; Cabelli, D. E.; Hart, P. J.; Culotta, V. C. Candida albicans SOD5 represents the prototype of an unprecedented class of Cu-only superoxide dismutases required for pathogen defense. Proc. Nat. Acad. Sci. 2014, 111, 5866-5871. DOI: 10.1073/pnas.1400137111
  • Shkrob, I. A.; Marin, T. W.; Wishart, J. F.; Grills, D. C., Radiation Stability of Cations in Ionic Liquids. 5. Task-Specific Ionic Liquids Consisting of Biocompatible Cations and the Puzzle of Radiation Hypersensitivity. J. Phys. Chem. B 2014, 118, 10477-10492. DOI: 10.1021/jp5049716
  • Wishart, J. F. Ionic Liquid Radiation Chemistry. In Ionic Liquids Further UnCOILed: Critical Expert Overviews, Plechkova, N.; Seddon, K. R., Eds. Wiley, Ltd.: Chichester, UK, 2014; pp259-274.
  • Li, X.; Bird, M.; Mauro, G.; Asaoka, S.; Cook, A. R.; Chen, H.-C.; Miller, J. R. "Transport of Triplet Excitons Along Continuous 100 nm Polyfluorene Chains" J. Phys. Chem. B 2014. DOI:10.1021/jp509396s
  • Zaikowski, L.; Mauro, G.; Bird, M.; Karten, B.; Asaoka, S.; Wu, Q.; Cook, A. R.; Miller, J. R."Charge Transfer Fluorescence and 34 nm Exciton Diffusion Length in Polymers with Electron Acceptor End Traps" J. Phys. Chem. B 2014. DOI: 10.1021/jp510095p
  • Mani, T.; Miller, J. R. "Role of Bad Dihedral Angles: Methylfluorenes Act as Energy Barriers for Excitons and Polarons of Oligofluorenes" J. Phys. Chem. A 2014, 118, 9451-9459. DOI:10.1021/jp5080626
  • Lall-Ramnarine, S. I.; Mukhlall, J. A.; Wishart, J. F.; Engel, R. R.; Romeo, A. R.; Gohdo, M.; Ramati, S.; Berman, M.; Suarez, S. N., Cyclic phosphonium ionic liquids, Beilstein Journal of Organic Chemistry 2014, 10, 271-275. DOI:10.3762/bjoc.10.22
  • Holroyd, R.; Miller, J. R.; Cook, A. R.; Nishikawa, M., Pressure Tuning of Electron Attachment to Benzoquinones in Nonpolar Fluids: Continuous Adjustment of Free Energy Changes, J. Phys. Chem. B 2014, 118, 2164-2171. DOI:10.1021/j100601a008
  • Bird, M. J.; Reid, O. G.; Cook, A. R.; Asaoka, S.; Shibano, Y.; Imahori, H.; Rumbles, G.; Miller, J. R., Mobility of Holes in Oligo- and Polyfluorenes of Defined Lengths, J. Phys. Chem. C 2014, 118, 6100-6109. DOI:10.1021/jp5010874
  • Bakalis, J.; Cook, A. R.; Asaoka, S.; Forster, M.; Scherf, U.; Miller, J. R., Polarons, Compressed Polarons, and Bipolarons in Conjugated Polymers, J. Phys. Chem. C 2014, 118, 114-125. DOI:10.1021/jp408910a

2013

  • Zamadar, M.; Cook, A. R.; Lewandowska-Andralojc, A.; Holroyd, R.; Jiang, Y.; Bikalis, J.; Miller, J. R., Electron Transfer by Excited Benzoquinone Anions: Slow Rates for Two-Electron Transitions, J. Phys. Chem. A 2013, 117, 8360-8367. DOI:10.1021/jp403113u
  • Zamadar, M.; Asaoka, S.; Grills, D. C.; Miller, J. R., Giant infrared absorption bands of electrons and holes in conjugated molecules, Nature Communications 2013, 4. DOI:10.1038/ncomms3818
  • Shkrob, I. A.; Marin, T. W.; Wishart, J. F., Ionic Liquids Based on Polynitrile Anions: Hydrophobicity, Low Proton Affinity, and High Radiolytic Resistance Combined, J. Phys. Chem. B 2013, 117, 7084-7094. DOI:10.1021/jp404313g
  • Shkrob, I. A.; Marin, T. W.; Hatcher, J. L.; Cook, A. R.; Szreder, T.; Wishart, J. F., Radiation Stability of Cations in Ionic Liquids. 2. Improved Radiation Resistance through Charge De localization in 1-Benzylpyridinium, J. Phys. Chem. B 2013, 117, 14385-14399. DOI:10.1021/jp408242b
  • Shkrob, I. A.; Marin, T. W.; Crowell, R. A.; Wishart, J. F., Photo- and Radiation-Chemistry of Halide Anions in Ionic Liquids, J. Phys. Chem. A 2013, 117, 5742-5756. DOI:10.1021/jp4042793
  • Kashyap, H. K.; Santos, C. S.; Murthy, N. S.; Hettige, J. J.; Kerr, K.; Ramati, S.; Gwon, J.; Gohdo, M.; Lall-Ramnarine, S. I.; Wishart, J. F.et. al., Structure of 1-Alky1-1-methylpyrrolidinium Bis(trifluoromethylsulfonyl)amide Ionic Liquids with Linear, Branched, and Cyclic Alkyl Groups, J. Phys. Chem. B 2013, 117, 15328-15337. DOI:10.1021/jp403518j
  • Johnson, J. C.; Akdag, A.; Zamadar, M.; Chen, X. D.; Schwerin, A. F.; Paci, I.; Smith, M. B.; Havlas, Z.; Miller, J. R.; Ratner, M. A.et. al., Toward Designed Singlet Fission: Solution Photophysics of Two Indirectly Coupled Covalent Dimers of 1,3-Diphenylisobenzofuran, J. Phys. Chem. B 2013, 117, 4680-4695. DOI:10.1021/jp310979q
  • Cook, A. R.; Bird, M. J.; Asaoka, S.; Miller, J. R., Rapid "Step Capture" of Holes in Chloroform during Pulse Radiolysis, J. Phys. Chem. A 2013, 117, 7712-7720. DOI:10.1021/jp405349u
  • Bao, J. H.; Yu, Z. H.; Gundlach, L.; Benedict, J. B.; Coppens, P.; Chen, H. C.; Miller, J. R.; Piotrowiak, P., Excitons and Excess Electrons in Nanometer Size Molecular Polyoxotitanate Clusters: Electronic Spectra, Exciton Dynamics, and Surface States, J. Phys. Chem. B 2013, 117, 4422-4430. DOI:10.1021/jp307724v

2012

  • Zaikowski, L.; Kaur, P.; Gelfond, C.; Selvaggio, E.; Asaoka, S.; Wu, Q.; Chen, H. C.; Takeda, N.; Cook, A. R.; Yang, A.et. al., Polarons, Bipolarons, and Side-By-Side Polarons in Reduction of Oligofluorenes, J. Am. Chem. Soc. 2012, 134, 10852-10863. DOI:10.1021/ja301494n
  • Wishart, J. F.; Funston, A. M.; Szreder, T.; Cook, A. R.; Gohdo, M., Electron solvation dynamics and reactivity in ionic liquids observed by picosecond radiolysis techniques, Faraday Discuss. 2012, 154, 353-363. DOI:10.1039/c1fd00065a
  • Takeda, N.; Miller, J. R., Poly(3-decylthiophene) Radical Anions and Cations in Solution: Single and Multiple Polarons and Their Delocalization Lengths in Conjugated Polymers, J. Phys. Chem. B 2012, 116, 14715-14723. DOI:10.1021/jp3096242
  • Shkrob, I. A.; Marin, T. W.; Chemerisov, S. D.; Hatcher, J.; Wishart, J. F., Toward Radiation-Resistant Ionic Liquids. Radiation Stability of Sulfonyl Imide Anions, J. Phys. Chem. B 2012, 116, 9043-9055. DOI:10.1021/jp302151c
  • Shkrob, I. A.; Marin, T. W.; Bell, J. R.; Luo, H. M.; Dai, S.; Hatcher, J. L.; Rimmer, R. D.; Wishart, J. F., Radiation-Induced Fragmentation of Diamide Extraction Agents in Ionic Liquid Diluents, J. Phys. Chem. B 2012, 116, 2234-2243. DOI:10.1021/jp2117483
  • Musat, R. M.; Cook, A. R.; Renault, J. P.; Crowell, R. A., Nanosecond Pulse Radiolysis of Nanoconfined Water, J. Phys. Chem. C 2012, 116, 13104-13110. DOI:10.1021/jp301000c
  • Lee, H. Y.; Issa, J. B.; Isied, S. S.; Castner, E. W.; Pan, Y. F.; Hussey, C. L.; Lee, K. S.; Wishart, J. F., A Comparison of Electron-Transfer Dynamics in Ionic Liquids and Neutral Solvents, J. Phys. Chem. C 2012, 116, 5198-5209. DOI:10.1021/jp208852r

2011

  • Thomas, M. F.; Li, L. L.; Handley-Pendleton, J. M.; van der Lelie, D.; Dunn, J. J.; Wishart, J. F., Enzyme activity in dialkyl phosphate ionic liquids, Bioresour. Technol. 2011, 102, 11200-11203. DOI:10.1016/j.biortech.2011.09.069
  • Sreearunothai, P.; Estrada, A.; Asaoka, S.; Kowalczyk, M.; Jang, S.; Cook, A. R.; Preses, J. M.; Miller, J. R., Triplet Transport to and Trapping by Acceptor End Groups on Conjugated Polyfluorene Chains, J. Phys. Chem. C 2011, 115, 19569-19577. DOI:10.1021/jp205828q
  • Shkrob, I. A.; Marin, T. W.; Chemerisov, S. D.; Wishart, J. F., Radiation Induced Redox Reactions and Fragmentation of Constituent Ions in Ionic Liquids. 1. Anions, J. Phys. Chem. B 2011, 115, 3872-3888. DOI:10.1021/jp2003062
  • Shkrob, I. A.; Marin, T. W.; Chemerisov, S. D.; Wishart, J. F., Radiation and Radical Chemistry of NO3-, HNO3, and Dialkylphosphoric Acids in Room-Temperature Ionic Liquids, J. Phys. Chem. B 2011, 115, 10927-10942. DOI:10.1021/jp206579j
  • Shkrob, I. A.; Marin, T. W.; Chemerisov, S. D.; Hatcher, J. L.; Wishart, J. F., Radiation Induced Redox Reactions and Fragmentation of Constituent Ions in Ionic Liquids. 2. Imidazolium Cations, J. Phys. Chem. B 2011, 115, 3889-3902. DOI:10.1021/jp200305b
  • Keller, J. M.; Glusac, K. D.; Danilov, E. O.; McIlroy, S.; Sreearuothai, P.; Cook, A. R.; Jiang, H.; Miller, J. R.; Schanze, K. S., Negative Polaron and Triplet Exciton Diffusion in Organometallic "Molecular Wires", J. Am. Chem. Soc. 2011, 133, 11289-11298. DOI:10.1021/ja202898p
  • Cook, A. R.; Sreearunothai, P.; Asaoka, S.; Miller, J. R., Sudden, "Step" Electron Capture by Conjugated Polymers, J. Phys. Chem. A 2011, 115, 11615-11623. DOI:10.1021/jp205790k
  • Castner, E. W.; Margulis, C. J.; Maroncelli, M.; Wishart, J. F. In Annual Review of Physical Chemistry, Vol 62; Leone, S. R., Cremer, P. S., Groves, J. T., Johnson, M. A., Eds. 2011; Vol. 62, p 85-105. DOI:10.1146/annurev-physchem-032210-103421

2010

  • Wishart, J. F., Ionic Liquids and Ionizing Radiation: Reactivity of Highly Energetic Species, J. Phys. Chem.Lett. 2010, 1, 3225-3231. DOI:10.1021/jz101096b
  • Stepinski, D. C.; Vandegrift, G. F.; Shkrob, I. A.; Wishart, J. F.; Kerr, K.; Dietz, M. L.; Qadah, D. T. D.; Garvey, S. L., Extraction of Tetra-Oxo Anions into a Hydrophobic, Ionic Liquid-Based Solvent without Concomitant Ion Exchange, Industrial & Engineering Chemistry Research 2010, 49, 5863-5868. DOI:10.1021/ie1000345
  • Shirota, H.; Fukazawa, H.; Fujisawa, T.; Wishart, J. F., Heavy Atom Substitution Effects in Non-Aromatic Ionic Liquids: Ultrafast Dynamics and Physical Properties, J. Phys. Chem. B 2010, 114, 9400-9412. DOI:10.1021/jp1021104
  • Shibano, Y.; Imahori, H.; Sreearunothai, P.; Cook, A. R.; Miller, J. R., Conjugated "Molecular Wire" for Excitons, J. Phys. Chem.Lett. 2010, 1, 1492-1496. DOI:10.1021/jz100380m
  • Schwerin, A. F.; Johnson, J. C.; Smith, M. B.; Sreearunothai, P.; Popovic, D.; Cerny, J.; Havlas, Z.; Paci, I.; Akdag, A.; MacLeod, M. K.et. al., Toward Designed Singlet Fission: Electronic States and Photophysics of 1,3-Diphenylisobenzofuran, J. Phys. Chem. A 2010, 114, 1457-1473.>DOI:10.1021/jp907401t
  • Krieger, B. M.; Lee, H. Y.; Emge, T. J.; Wishart, J. F.; Castner, E. W., Ionic liquids and solids with paramagnetic anions, PCCP 2010, 12, 8919-8925. DOI:10.1039/b920652n
  • Grills, D. C.; Cook, A. R.; Fujita, E.; George, M. W.; Preses, J. M.; Wishart, J. F., Application of External-Cavity Quantum Cascade Infrared Lasers to Nanosecond Time-Resolved Infrared Spectroscopy of Condensed-Phase Samples Following Pulse Radiolysis, Appl. Spectrosc. 2010, 64, 563-570. DOI:10.1366/000370210791414344

2009

  • Castner, E. W.; Wishart, J. F., Spotlight on ionic liquids, J. Chem. Phys. 2010, 132. DOI:10.1063/1.3373178
  • Wishart, J. F.; Shkrob, I. A. In Ionic Liquids: From Knowledge to Application; Plechkova, N. V., Rogers, R. D., Seddon, K. R., Eds. 2009; Vol. 1030, p 119-134. DOI:10.1021/bk-2009-1030
  • Wishart, J. F., Energy applications of ionic liquids, Energy & Environmental Science 2009, 2, 956-961.  DOI:10.1039/b906273d
  • Takahashi, K.; Tezuka, H.; Satoh, T.; Katsumura, Y.; Watanabe, M.; Crowell, R. A.; Wishart, J. F., Kinetic Salt Effects on an Ionic Reaction in Ionic Liquid/Methanol Mixtures-Viscosity and Coulombic Screening Effects, Chem. Lett. 2009, 38, 236-237. DOI:10.1246/cl.2009.236
  • Takahashi, K.; Suda, K.; Seto, T.; Katsumura, Y.; Katoh, R.; Crowell, R. A.; Wishart, J. F., Photo-detrapping of solvated electrons in an ionic liquid, Radiat. Phys. Chem. 2009, 78, 1129-1132. DOI:10.1016/j.radphyschem.2009.07.016
  • Strehmel, V.; Wishart, J. F.; Polyansky, D. E.; Strehmel, B., Recombination of Photogenerated Lophyl Radicals in Imidazolium-Based Ionic Liquids, Chemphyschem 2009, 10, 3112-3118. DOI:10.1002/cphc.200900594
  • Sreearunothai, P.; Asaoka, S.; Cook, A. R.; Miller, J. R., Length and Time-Dependent Rates in Diffusion-Controlled Reactions with Conjugated Polymers, J. Phys. Chem. A 2009, 113, 2786-2795.  DOI:10.1021/jp80413x
  • Shkrob, I. A.; Wishart, J. F., Charge Trapping in Imidazolium Ionic Liquids, J. Phys. Chem. B 2009, 113, 5582-5592. DOI:10.1021/jp811495e
  • Lall-Ramnarine, S. I.; Castano, A.; Subramaniam, G.; Thomas, M. F.; Wishart, J. F., Synthesis, characterization and radiolytic properties of bis(oxalato)borate containing ionic liquids, Radiat. Phys. Chem. 2009, 78, 1120-1125. DOI:10.1016/j.radphyschem.2009.02.007
  • Holroyd, R. A.; Cook, A. R.; Preses, J. M., Dynamics of excimer formation and decay in supercritical krypton, J. Chem. Phys. 2009, 131. DOI:10.1063/1.3266942
  • Cook, A. R.; Shen, Y. Z., Optical fiber-based single-shot picosecond transient absorption spectroscopy, Rev. Sci. Instrum. 2009, 80. DOI:10.1063/1.3156048
  • Justus, E.; Rischka, M.; Wishart, J. F.; Werner, K.; Gabel, D., Trialkylammoniododecaborates: Anions for ionic liquids with potassium, lithium and protons as cations, Chem. Eur. J. 2008, 14, 1918-1923. DOI:10.1002/chem.200701427

2008

  • Justus, E.; Rischka, M.; Wishart, J. F.; Werner, K.; Gabel, D. “Trialkylammoniododecaborates: Anions for ionic liquids with potassium, lithium and protons as cations” -Eur. J. 2008, 14, 1918-1923. DOI:10.1002/chem.200701427
  • Poskrebyshev, G. A.; Shafirovich, V.; Lymar, S. V. “Disproportionation pathways of aqueous hyponitrite radicals (HN2O2/N2O2 ·-)” J. Phys. Chem. A 2008, 112, 8295-8302. DOI:10.1021/jp803230c
  • “Tools for radiolysis studies” J. F. Wishart in “Radiation chemistry: from basics to applications in material and life sciences” Spotheim-Maurizot, M., Douki, T., Mostafavi, M., and Belloni, J., Eds.; L'Actualité Chimique Livres, Paris, (2008) Ch. 2, pp. 17-33. [Information about the book]
  • Abreu, I. A.; Hearn, A.; An, H.; Nick, H. S.; Silverman, D. N.; Cabelli, D. E. “The Kinetic Mechanism of Manganese-Containing Superoxide Dismutase from Deinococcus radiodurans: A Specialized Enzyme for the Elimination of High Superoxide Concentrations” Biochemistry 2008, 47, 2350-2356. DOI:10.1021/bi7016206
  • Barnese, K.; Gralla, E. B.; Cabelli, D. E.; Valentine, J. S. “Manganous Phosphate is a Superoxide Dismutase” Am. Chem. Soc. 2008, 130, 4604-4606. DOI:10.1021/ja710162n
  • Noorhasan, N. N.; Sharma, V. K.; Cabelli, D. E. “Reactivity of Ferrate(V) (FeVO43-) with Aminopolycarboxylates in Alkaline medium: Premix Pulse Radiolysis” Chim. Acta 2008, 361, 1041-1046. DOI:10.1016/j.ica.2007.07.019
  • Quint, P. S.; Domsic, J.; Cabelli, D. E.; McKenna, R.; Silverman, D. N. “Role of a Glutamate Bridge Spanning the Dimeric Interface of Human Manganese Superoxide Dismutase Biochemistry” Biochemistry 2008, 47, 4621-4628. DOI:10.1021/bi7024518
  • Rodrigues, J. V.; Teixeira, M.; Saraiva, L. M.; Soares, C. M.; Victor, B. L.; Cabelli, D. E.; Huber, H. “Superoxide reduction by Nanoarqueum equitans neelaredoxin, a “natural mutant” lacking the ferric sixth ligand glutamate” Biol. Inorg. Chem. 2008, 13, 219-228. DOI:10.1007/s00775-007-0313-z
  • Sharma, V. K.; Yngard, R. A.; Cabelli, D. E.; Baum, J. C. “Ferrate(VI) and Ferrate(V) Oxidation of Cyanide, Thiocyanate, and Copper(I) Cyanide” Phys. Chem. 2008, 77, 761-767. DOI:10.1016/j.radphyschem.2007.11.004
  • Sharma, V. K.; Cabelli, D. E. “Aqueous High Oxidation State Iron: Generation and Reactivity” In Ferrates: Synthesis, Properties and Applications in Water and Water Treatment; Sharma, V. K., Ed.; American Chemical Society: Washington, D.C., 2008. DOI:1021/bk-2008-0985.ch010
  • Rosokha, S. V.; Newton, M. D.; Jalilov, A. S.; Kochi, J. K. “The spectral elucidation versus the X-ray structure of the critical precursor complex in bimolecular electron transfers: Application of Experimental/Theoretical solvent probes to Ion-radical (Redox) dyads” Am. Chem. Soc. 2008, 130, 1944-1952. DOI:10.1021/ja076591b
  • Wang, Q.; Newton, M. D. “Structure, energetics, and electronic coupling in the (TCNE2)-. encounter complex in solution: A polarizable continuum study” Phys. Chem. B 2008, 112, 568-576. DOI:10.1021/jp0753528
  • Jin, H.; O'Hare, B.; Dong, J.; Arzhantsev, S.; Baker, G. A.; Wishart, J. F.; Benesi, A. J.; Maroncelli, M., Physical properties of ionic liquids consisting of the 1-butyl-3-methylimidazolium cation with various anions and the bis(trifluoromethylsulfonyl)imide anion with various cations, J. Phys. Chem. B 2008, 112, 81-92. DOI:10.1021/jp076462h
  • Asaoka, S.; Takeda, N.; Lyoda, T.; Cook, A. R.; Miller, J. R., Electron and hole transport to trap groups at the ends of conjugated polyfluorenes, J. Am. Chem. Soc. 2008, 130, 11912-11920. DOI:10.1021/ja800426z

About the EPIP Group

We apply both photoexcitation and ionization by short pulses of fast electrons to investigate fundamental chemical problems relevant to the production and efficient use of energy.